Thiolato-complexes of the transition metals
作者： P.J. Blower , J.R. Dilworth
DOI: 10.1016/0010-8545(87)85003-8
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摘要: A. Introduction B. Complexes with terminal thiolato-ligands (i) Mononuclear homoleptic complexes monoand bi-dentate thiolates _ (ii) heteroligands (a) Oxo-complexes (b) metal-nitrogen multiple bonds (c) Miscellaneous monomeric thiolato other . (iii) sterically hindered Chromium, molybdenum and tungsten Manganese, technetium rhenium Iron, ruthenium osmium. (d) Cobalt, rhodium iridium. (e) Copper, silver gold C. CL’-bridging Dinuclear linear polynuclear two p2-thiolato-ligands Molybdenum ..... Iron Cobalt Nickel, palladium platinum (f) gold. (g) Zinc, cadmium mercury three Ir_2-thiolato-ligands (iv) quadruple r2-thiolato-ligands (v) Three-dimensional clusters Clusters tetrahedral metal centres Copper Other cluster types D. p’-bridging E. Synthesis of thiolato-complexes
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