Effect of ionization potential change in poly(3,4-ethylenedioxythiophene):poly(styrenesulfonic acid) on the performance of polymer light emitting diodes due to its reaction with indium tin oxide

作者: Chih-Hao Chang , Show-An Chen

DOI: 10.1063/1.2759474

关键词:

摘要: Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonic acid) (PEDOT:PSS) is usually used to facilitate hole injection in polymer light emitting diodes. The authors ultraviolet photoelectron spectroscopy investigate ionization potential (IP) changes of PEDOT:PSS spin coated on indium tin oxide (ITO), and found that increasing delay time baking after coating decreases its IP increases barrier polymer. change attributed dedoping PEDOT due reaction ITO with protons PSS those doped the presence water. To get good performance bipolar device, film should be baked right coating.

参考文章(9)
Kenji Kawano, Roberto Pacios, Dmitry Poplavskyy, Jenny Nelson, Donal DC Bradley, James R Durrant, None, Degradation of organic solar cells due to air exposure Solar Energy Materials and Solar Cells. ,vol. 90, pp. 3520- 3530 ,(2006) , 10.1016/J.SOLMAT.2006.06.041
Chih-Hao Chang, Jin-Long Liao, Ming-Chin Hung, Show-An Chen, None, Interface formation between poly(9,9-dioctylfluorene) and poly(3,4-ethylenedioxythiophene):poly(styrenesulfonic acid) Applied Physics Letters. ,vol. 90, pp. 063506- ,(2007) , 10.1063/1.2456815
Ka Wai Wong, HL Yip, Yi Luo, KY Wong, WM Lau, KH Low, HF Chow, ZQ Gao, WL Yeung, CC Chang, None, Blocking reactions between indium-tin oxide and poly (3,4-ethylene dioxythiophene):poly(styrene sulphonate) with a self-assembly monolayer Applied Physics Letters. ,vol. 80, pp. 2788- 2790 ,(2002) , 10.1063/1.1469220
K.Z. Xing, M. Fahlman, X.W. Chen, O. Inganäs, W.R. Salaneck, The electronic structure of poly(3,4-ethylene-dioxythiophene): studied by XPS and UPS Synthetic Metals. ,vol. 89, pp. 161- 165 ,(1997) , 10.1016/S0379-6779(97)81212-X
C.H.L. Weijtens, V. van Elsbergen, M.M. de Kok, S.H.P.M. de Winter, Effect of the alkali metal content on the electronic properties of PEDOT:PSS Organic Electronics. ,vol. 6, pp. 97- 104 ,(2005) , 10.1016/J.ORGEL.2005.02.005
M. M. de Kok, M. Buechel, S. I. E. Vulto, P. van de Weijer, E. A. Meulenkamp, S. H. P. M. de Winter, A. J. G. Mank, H. J. M. Vorstenbosch, C. H. L. Weijtens, V. van Elsbergen, Modification of PEDOT:PSS As Hole Injection Layer in Polymer LEDs Physica Status Solidi (a). ,vol. 201, pp. 1342- 1359 ,(2004) , 10.1002/PSSA.200404338
M. P. de Jong, L. J. van IJzendoorn, M. J. A. de Voigt, Stability of the interface between indium-tin-oxide and poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) in polymer light-emitting diodes Applied Physics Letters. ,vol. 77, pp. 2255- 2257 ,(2000) , 10.1063/1.1315344