Highly efficient polyoxometalate-based catalysts for clean-gasoline synthesis
作者： Chunling Wang , Cheng Liu , Yunhang Hu , Xianni Bu , Tiejun Zhao
DOI: 10.1039/C5TA05344G
关键词:
摘要: Poor selectivity for gasoline products is a critical issue the Fischer–Tropsch synthesis (FTS). Herein, we report that introduction of polyoxometalate Cs2.5H0.5PW12O40 (CsPW) into conventional FTS catalyst (Co/Al2O3) can create highly efficient bifunctional catalyst, leading to 118% increase in gasoline. Furthermore, it was found such significant improvement due effective hydrocracking heavier hydrocarbon at CsPW sites.
rsc.org
sci-hub.se 参考文章(33)
Juan C. Yori, Javier M. Grau, Viviana M. Benítez, Jorge Sepúlveda, Hydroisomerization-cracking of n-octane on heteropolyacid H3PW12O40 supported on ZrO2, SiO2 and carbon: Effect of Pt incorporation on catalyst performance Applied Catalysis A-general. ,vol. 286, pp. 71- 78 ,(2005) , 10.1016/J.APCATA.2005.03.003
J. R. Rostrup-Nielsen, Making Fuels from Biomass Science. ,vol. 308, pp. 1421- 1422 ,(2005) , 10.1126/SCIENCE.1113354
Qinghong Zhang, Weiping Deng, Ye Wang, Recent advances in understanding the key catalyst factors for Fischer-Tropsch synthesis Journal of Energy Chemistry. ,vol. 22, pp. 27- 38 ,(2013) , 10.1016/S2095-4956(13)60003-0
Abhishek Banerjee, Bassem S. Bassil, Gerd-Volker Röschenthaler, Ulrich Kortz, Diphosphates and diphosphonates in polyoxometalate chemistry. Chemical Society Reviews. ,vol. 41, pp. 7590- 7604 ,(2012) , 10.1039/C2CS35153F
Zhiqiang Yang, Shujing Guo, Xiulian Pan, Junhu Wang, Xinhe Bao, FeN nanoparticles confined in carbon nanotubes for CO hydrogenation Energy and Environmental Science. ,vol. 4, pp. 4500- 4503 ,(2011) , 10.1039/C1EE01428E
Nataliya V. Maksimchuk, Konstantin A. Kovalenko, Sergey S. Arzumanov, Yurii A. Chesalov, Maxim S. Melgunov, Alexander G. Stepanov, Vladimir P. Fedin, Oxana A. Kholdeeva, Hybrid polyoxotungstate/MIL-101 materials: synthesis, characterization, and catalysis of H2O2-based alkene epoxidation. Inorganic Chemistry. ,vol. 49, pp. 2920- 2930 ,(2010) , 10.1021/IC902459F
Chuang Xing, Guohui Yang, Mingbo Wu, Ruiqin Yang, Li Tan, Pengfei Zhu, Qinhong Wei, Jie Li, Jianwei Mao, Yoshiharu Yoneyama, Noritatsu Tsubaki, None, Hierarchical zeolite Y supported cobalt bifunctional catalyst for facilely tuning the product distribution of Fischer–Tropsch synthesis Fuel. ,vol. 148, pp. 48- 57 ,(2015) , 10.1016/J.FUEL.2015.01.040
Kei Inumaru, Toru Ishihara, Yuichi Kamiya, Toshio Okuhara, Shoji Yamanaka, Water‐Tolerant, Highly Active Solid Acid Catalysts Composed of the Keggin‐Type Polyoxometalate H3PW12O40 Immobilized in Hydrophobic Nanospaces of Organomodified Mesoporous Silica Angewandte Chemie. ,vol. 46, pp. 7625- 7628 ,(2007) , 10.1002/ANIE.200702478
X.K. Yang, L.F. Chen, J.A. Wang, L.E. Noreña, O. Novaro, Study of the Keggin structure and catalytic properties of Pt-promoted heteropoly compound/Al-MCM-41 hybrid catalysts Catalysis Today. ,vol. 148, pp. 160- 168 ,(2009) , 10.1016/J.CATTOD.2009.03.022
Reza M. Malek Abbaslou, Ahmad Tavassoli, Jafar Soltan, Ajay K. Dalai, Iron catalysts supported on carbon nanotubes for Fischer–Tropsch synthesis: Effect of catalytic site position Applied Catalysis A: General. ,vol. 367, pp. 47- 52 ,(2009) , 10.1016/J.APCATA.2009.07.025