The atmospheric corrosion of quaternary bronzes: The leaching action of acid rain

作者: E. Bernardi , C. Chiavari , B. Lenza , C. Martini , L. Morselli

DOI: 10.1016/J.CORSCI.2008.10.008

关键词:

摘要: Abstract The effect of leaching rain on the corrosion behaviour bronze UNSC83600 was investigated as to influence alloying elements (Cu, Sn, Zn, Pb) through dropping tests simulating a severe runoff condition with solution reproducing natural acid rain. Corrosion followed time monitoring both samples and solutions (up 30 days) by SEM, EDS, Raman spectroscopy, XRD, AAS. patina behaves porous layer enriched in stable tin compounds allowing uniform dissolution Cu, Zn partly Pb. Laboratory results are good agreement field studies outdoor bronzes unsheltered condition.

参考文章(41)
Lyman G. Roglesfield, Acid Rain Research Focus ,(2009)
Z Iqbal, S Veprek, Raman scattering from hydrogenated microcrystalline and amorphous silicon Journal of Physics C: Solid State Physics. ,vol. 15, pp. 377- 392 ,(1982) , 10.1088/0022-3719/15/2/019
M. T. Sougrati, S. Jouen, B. Hannoyer, A. Barbier, A Study of Copper and Copper Alloys Runoff in Urban Atmosphere Wiley-VCH. pp. 130- 136 ,(2007) , 10.1002/9783527610327.CH17
Cunyi Xie, Lide Zhang, Chimei Mo, Characterization of Raman spectra in nano-SnO2 solids Physica Status Solidi (a). ,vol. 141, ,(1994) , 10.1002/PSSA.2211410138
L. M. M. dos Santos, M. M. Lemos Salta, I. T. E. Fonseca, The electrochemical behaviour of bronze in synthetic seawater Journal of Solid State Electrochemistry. ,vol. 11, pp. 259- 266 ,(2007) , 10.1007/S10008-006-0102-6
K.P. FitzGerald, J. Nairn, G. Skennerton, A. Atrens, Atmospheric corrosion of copper and the colour, structure and composition of natural patinas on copper Corrosion Science. ,vol. 48, pp. 2480- 2509 ,(2006) , 10.1016/J.CORSCI.2005.09.011
W He, I Odnevall Wallinder, Christofer Leygraf, None, A laboratory study of copper and zinc runoff during first flush and steady-state conditions Corrosion Science. ,vol. 43, pp. 127- 146 ,(2001) , 10.1016/S0010-938X(00)00066-4
L. M. Sharygin, S. M. Vovk, Raman spectroscopy studies of structural changes in hydrated titanium and tin dioxide gels under drying Journal of Applied Spectroscopy. ,vol. 64, pp. 283- 286 ,(1997) , 10.1007/BF02675157
C. Debiemme-Chouvy, F. Ammeloot, E.M.M. Sutter, X-ray photoemission investigation of the corrosion film formed on a polished Cu–13Sn alloy in aerated NaCl solution Applied Surface Science. ,vol. 174, pp. 55- 61 ,(2001) , 10.1016/S0169-4332(01)00023-X