Interlinking supertetrahedral chalcogenolate clusters with bipyridines to form two-dimensional coordination polymers for photocatalytic degradation of organic dye
作者： Chao Xu , Ming-Ming Sheng , Hua-Tian Shi , Maria Strømme , Qian-Feng Zhang
DOI: 10.1039/C9DT00480G
关键词:
摘要: Chalcogenolate clusters Cd6Ag4(EPh)16(DMF)3(CH3OH) (E = S, Se) with supertetrahedral structures are isolated. Further interlinking the organic linker 4,4′-trimethylenedipiperidine in stepwise assembly approach forms two-dimensional coordination polymers. The and polymers show tunable band gaps efficient photocatalytic activities for degradation of aqueous dye solution. This study demonstrates great potential using chalcogenolate their photocatalysis applications.
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crystallography.net参考文章(47)
Silke Behrens, Marco Bettenhausen, Andreas Eichhöfer, Dieter Fenske, Synthesis and Crystal Structure of[Cd10Se4(SePh)12(PPh3)4] and[Cd16(SePh)32(PPh3)2] Angewandte Chemie International Edition in English. ,vol. 36, pp. 2797- 2799 ,(1997) , 10.1002/ANIE.199727971
Chao Xu, Jing-Jing Zhang, Qun Chen, Taike Duan, Wa-Hung Leung, Qian-Feng Zhang, Polynuclear heterometallic cadmium(II)/silver(I) phenylthiolates: Syntheses and structures of [Cd3(μ-SPh)6(μ3-SPh)4Ag4(PPh3)4] and [Cd3(OMe)2(μ-SPh)4(μ3-SPh)8Ag8(μ-dppp)4] (dppp = 1,3-bis(disphenylphosphino)propane) Inorganic Chemistry Communications. ,vol. 15, pp. 308- 310 ,(2012) , 10.1016/J.INOCHE.2011.11.012
Garry S. H. Lee, Don C. Craig, Ida. Ma, Marcia L. Scudder, Trevor D. Bailey, Ian G. Dance, [S4Cd17(SPh)28]2-, the first member of a third series of tetrahedral [SWMX(SR)y]z- clusters Journal of the American Chemical Society. ,vol. 110, pp. 4863- 4864 ,(1988) , 10.1021/JA00222A075
Qichun Zhang, Xianhui Bu, Zhien Lin, Tao Wu, Pingyun Feng, Organization of tetrahedral chalcogenide clusters using a tetrahedral quadridentate linker. Inorganic Chemistry. ,vol. 47, pp. 9724- 9726 ,(2008) , 10.1021/IC800588Q
Chao Xu, Jing-Jing Zhang, Tai-Ke Duan, Qun Chen, Wa-Hung Leung, Qian-Feng Zhang, Construction of heterobimetallic Cd(Hg)/Cu(Ag)/S(Se) complexes from homoleptic [Hg(EPh)2] molecules and [Cd(EPh)4]2− anions (E=S, Se) Polyhedron. ,vol. 33, pp. 185- 193 ,(2012) , 10.1016/J.POLY.2011.11.046
Nanfeng Zheng, Xianhui Bu, Jason Lauda, Pingyun Feng, None, Zero- and two-dimensional organization of tetrahedral cadmium chalcogenide clusters with bifunctional covalent linkers Chemistry of Materials. ,vol. 18, pp. 4307- 4311 ,(2006) , 10.1021/CM060557Z
Nanfeng Zheng, Xianhui Bu, Haiwei Lu, Qichun Zhang, Pingyun Feng, None, Crystalline superlattices from single-sized quantum dots Journal of the American Chemical Society. ,vol. 127, pp. 11963- 11965 ,(2005) , 10.1021/JA053588O
Nanfeng Zheng, Xianhui Bu, Pingyun Feng, Synthetic design of crystalline inorganic chalcogenides exhibiting fast-ion conductivity Nature. ,vol. 426, pp. 428- 432 ,(2003) , 10.1038/NATURE02159
Chao Xu, Yan-Gong Han, Taike Duan, Qian-Feng Zhang, Wa-Hung Leung, Two-dimensional assembly of the type Cd10Te4 thiolate cluster with 4,4′-trimethylenedipyridine Inorganic Chemistry Communications. ,vol. 12, pp. 1053- 1056 ,(2009) , 10.1016/J.INOCHE.2009.08.018
Qichun Zhang, Yang Liu, Xianhui Bu, Tao Wu, Pingyun Feng, A rare (3,4)-connected chalcogenide superlattice and its photoelectric effect. Angewandte Chemie. ,vol. 47, pp. 113- 116 ,(2008) , 10.1002/ANIE.200703442