Dynamical solvent effects on electron-transfer processes: recent progress and perspectives
作者： Michael J. Weaver , George E. McManis
DOI: 10.1021/AR00177A005
关键词:
摘要: Abstract : Recent advances in theoretical and experimental aspects of dynamical solvent effects activated electron-transfer processes are discussed, along with future research prospects. The last decade has seen a remarkable upsurge interest the role liquid-state chemical processes. Along intrinsic importance such phenomena chemistry biology, these activities have been fostered by substantial recent developments both nature. central concept 'friction', whereby collective motion necessary to surmount activation barrier slows rate below that expected from transition-state theory (TST), 1a-c spawned myriad treatments attempt describe effective solvation dynamics.
acs.org
sci-hub.se 参考文章(90)
K.E. Arnold, J. Yarwood, A.H. Price, Studies of molecular motions and interactions in acetonitrile Molecular Physics. ,vol. 48, pp. 451- 469 ,(1983) , 10.1080/00268978300100331
Roger M. Nielson, Michael J. Weaver, The role of solvent dynamics in electron transfer Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. ,vol. 260, pp. 15- 24 ,(1989) , 10.1016/0022-0728(89)87095-0
Norman Sutin, Theory of Electron Transfer Reactions: Insights and Hindsights Progress in Inorganic Chemistry. ,vol. 30, pp. 441- 498 ,(2007) , 10.1002/9780470166314.CH9
Mark Maroncelli, Graham R. Fleming, Picosecond solvation dynamics of coumarin 153: The importance of molecular aspects of solvation Journal of Chemical Physics. ,vol. 86, pp. 6221- 6239 ,(1987) , 10.1063/1.452460
Curtis F. Chapman, Richard S. Fee, Mark. Maroncelli, Solvation dynamics in N-methylamides The Journal of Physical Chemistry. ,vol. 94, pp. 4929- 4935 ,(1990) , 10.1021/J100375A032
Roger M. Nielson, M. Neal. Golovin, George E. McManis, Michael J. Weaver, The Orbital-Overlap Factor in Electron Transfer. Sensitivity of Homogeneous Self-Exchange Kinetics for Some Metallocenes to Electronic Structure. Journal of the American Chemical Society. ,vol. 110, pp. 1745- 1749 ,(1988) , 10.1021/JA00214A014
James T. Hynes, Outer-sphere electron-transfer reactions and frequency-dependent friction The Journal of Physical Chemistry. ,vol. 90, pp. 3701- 3706 ,(1986) , 10.1021/J100407A044
Massimo. Sparpaglione, Shaul. Mukamel, Adiabatic vs. nonadiabatic electron transfer and longitudinal solvent dielectric relaxation: Beyond the Debye model The Journal of Physical Chemistry. ,vol. 91, pp. 3938- 3943 ,(1987) , 10.1021/J100299A005
S. K. Garg, C. P. Smyth, Microwave Absorption and Molecular Structure in Liquids. LXII. The Three Dielectric Dispersion Regions of the Normal Primary Alcohols1 The Journal of Physical Chemistry. ,vol. 69, pp. 1294- 1301 ,(1965) , 10.1021/J100888A033
Andrzej Kapturkiewicz, Marcin Opałło, Medium effect in the electroreduction of nitromesitylene Journal of Electroanalytical Chemistry. ,vol. 185, pp. 15- 28 ,(1985) , 10.1016/0368-1874(85)85838-X