A Novel Solvothermal Route to Nanocrystalline Sn4P3 with Red Phosphorous as Raw Material
作者： Xiang Huang , Jiao Jiao Sun , He Huang , Bo Wang
DOI: 10.4028/WWW.SCIENTIFIC.NET/AMR.704.241
关键词:
摘要: Nanocrystalline tin phosphide Sn4P3 was synthesized from red phosphorus and tin chloride SnCl22H2O by a low temperature (200°C) solvothermal reaction in ethanolamine for only 10 hours. The important parameters of solvothermal processmolar ratio of initial components (P/Sn), temperature and duration were investigated. The phase, composition and morphology of the products were characterized by X-ray diffraction (XRD), energy dispersive spectroscopy (EDS) and transmission electron microscopy (TEM). The ideal solvothermal conditions to synthesize pure and nanocrystallined Sn4P3 were summarized in this work.
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