The first spiroconjugated TTF- and TCNQ-type molecules: a new class of electroactive systems?
作者： Pilar Sandín , Angeles Martínez-Grau , Luis Sánchez , Carlos Seoane , Rosendo Pou-Amérigo
DOI: 10.1021/OL047681D
关键词:
摘要: [Structure: see text] Spiroconjugated TTF-type electron donors (13a-c) and TCNQ-type acceptors (10, 11) have been prepared from spiroquinone 9. Cyclic voltammetry reveals a relatively weak accepting ability for 10 11, strong electron-donor character 13a-c. Whereas the spiroconjugation introduces destabilization of LUMO compounds 9-11, opposite is observed compound 13, thus justifying redox potential values.
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