Carbon−Oxygen Bond Formation between a Terminal Alkoxo Ligand and a Coordinated Olefin. Evidence for Olefin Insertion into a Rhodium Alkoxide
作者： Pinjing Zhao , Christopher D. Incarvito , John F. Hartwig
DOI: 10.1021/JA063347W
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摘要: Preparation and reactivity of a series bis(phosphine) rhodium(I) alkoxides stabilized by intramolecular olefin coordination are reported. {Rh(PEt3)2[κ1:η2-OCRR‘(CH2)nCHCH2]} (n = 1, 2) were prep...
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