Cationic palladium(II)–diphosphine complexes as catalysts for the carbonylation of alkenes to ketones
作者： Carmelina Pisano , Giambattista Consiglio , Angelo Sironi , Massimo Moret
DOI: 10.1039/C39910000421
关键词:
摘要: Cation palladium complexes of the type [(dppp)Pd(solvent)2][X]22[X = non or weakly coordinating anion; dppp 1,3-bis(diphenylphosphino)propane] are active catalysts for carbonylaion to ketones, e.g., seletive formation E-1,5-diphenylpent-l-en-3-one from styrene; in presence water and depending on acidity conditions dimerisation much less catalytically [(dppp)Pd(µ-OH)2 Pd(dppp)]X23 takes place, structure which was determined by X-ray crystallography.
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sci-hub.se 参考文章(12)
Ayusman Sen, Ta Wang Lai, Novel palladium(II)-catalyzed copolymerization of carbon monoxide with olefins Journal of the American Chemical Society. ,vol. 104, pp. 3520- 3522 ,(1982) , 10.1021/JA00376A053
Günther Oehme, Horst Pracejus, An efficient palladium(II) based catalytic system for the dimerization of methyl acrylate promoted by silver tetrafluoroborate and p-benzoquinone Journal of Organometallic Chemistry. ,vol. 320, ,(1987) , 10.1016/0022-328X(87)85070-2
G. W. Bushnell, The crystal structure of a dinuclear platinum(II) complex with a bent dihydroxy bridge, di-(μ-hydroxy)tetrakis(triethylphosphine)diplatinum(II).tetrafluoroborate Canadian Journal of Chemistry. ,vol. 56, pp. 1773- 1778 ,(1978) , 10.1139/V78-287
S Wimmer, P Castan, FL Wimmer, NP Johnson, None, Aqueous chemistry of Pt(II) and Pd(II) complexes of 2,2′-bipyridine and 1,10-phenanthroline: pH dependence Inorganica Chimica Acta. ,vol. 142, pp. 13- 15 ,(1988) , 10.1016/S0020-1693(00)80648-9
Shunichi Murahashi, Yoshiki Makabe, Kazuto Kunita, Palladium(0)-catalyzed rearrangement of N-allyl enamines. Synthesis of .delta.,.epsilon.-unsaturated imines and .gamma.,.delta.-unsaturated carbonyl compounds Journal of Organic Chemistry. ,vol. 53, pp. 4489- 4495 ,(1988) , 10.1021/JO00254A013
Ta Wang Lai, Ayusman Sen, Palladium(II)-catalyzed copolymerization of carbon monoxide with ethylene: direct evidence for a single mode of chain growth Organometallics. ,vol. 3, pp. 866- 870 ,(1984) , 10.1021/OM00084A007
Franz L Wimmer, Smita Wimmer, None, On the stability of palladium(II) aquo complexes with 2,2′-bipyridyl and 1,10-phenanthroline Inorganica Chimica Acta. ,vol. 149, pp. 1- 3 ,(1988) , 10.1016/S0020-1693(00)90558-9
Konstantin. Siegmann, Paul S. Pregosin, Luigi M. Venanzi, Reaction of organoboron compounds with platinum(II) disolvento complexes Organometallics. ,vol. 8, pp. 2659- 2664 ,(1989) , 10.1021/OM00113A023
Gordon William Bushnell, Keith Roger Dixon, Robert George Hunter, John James McFarland, Hydroxy Complexes of Platinum(II) and Palladium(II) Canadian Journal of Chemistry. ,vol. 50, pp. 3694- 3699 ,(1972) , 10.1139/V72-584
Fabrizio Gorla, Luigi M. Venanzi, Cationic Palladium(II), Platinum(II), and Rhodium(I) Complexes as Acetalisation Catalysts Helvetica Chimica Acta. ,vol. 73, pp. 690- 697 ,(1990) , 10.1002/HLCA.19900730317