The graphite filter furnace: a new atomization concept for atomic spectroscopy

作者: D.A. Katskov , R.I. McCrindle , R. Schwarzer , P.J.J.G. Marais

DOI: 10.1016/0584-8547(95)01339-3

关键词:

摘要: A new atomization concept for electrothermal atomic absorption spectroscopy (ETAAS) is proposed and discussed. The basic idea to form within part of an atomizer a large surface over which the collection fine particles sample be distributed, constrain vapor exit from that analytical zone. For amounts analyte are in range ordinary ETAAS, these techniques do not affect character release because area smaller than passage. However, when there excess matrix, this technique creates conditions matrix saturation impedes evaporation. This turn restricts concentration zone and, respectively, limits spectral background gas-phase chemical interferences. realized design graphite filter furnace. principle operation practical methods obtain advantages discussed compared, using experimental data.

参考文章(7)
J.C. Brice, Condensation and evaporation Solid-State Electronics. ,vol. 7, pp. 489- 489 ,(1964) , 10.1016/0038-1101(64)90049-8
Alan R. Date, Yuk Ying Cheung, Marianne E. Stuart, The influence of polyatomic ion interferences in analysis by inductively coupled plasma source mass spectrometry (ICP-MS) Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 42, pp. 3- 20 ,(1987) , 10.1016/0584-8547(87)80045-9
Dmitry A. Katskov, Rudolph Schwarzer, Pieter J. J. G. Marais, Robert I. McCrindle, Use of a furnace with a graphite filter for electrothermal atomic absorption spectrometry Journal of Analytical Atomic Spectrometry. ,vol. 9, pp. 431- 436 ,(1994) , 10.1039/JA9940900431
W. Frech, S. Jonsson, A new furnace design for constant temperature electrothermal atomic absorption spectroscopy Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 37, pp. 1021- 1028 ,(1982) , 10.1016/0584-8547(82)80031-1
B.V. L'vov, V.G. Nikolaev, E.A. Norman, L.K. Polzik, M. Mojica, Theoretical calculation of the characteristic mass in graphite furnace atomic absorption spectrometry Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 41, pp. 1043- 1053 ,(1986) , 10.1016/0584-8547(86)80125-2
Darryl D. Siemer, Leroy C. Lewis, Characterization of two modified carbon rod atomizers for atomic absorption spectrometry Analytical Chemistry. ,vol. 55, pp. 99- 104 ,(1983) , 10.1021/AC00252A027