Application of a Novel DOPO-Based Polymeric Phosphate Flame Retardant for Polycarbonate/Acrylonitrile-butadiene-styrene Alloy
作者： Li Yan , Ji Meng Sang
DOI: 10.4028/WWW.SCIENTIFIC.NET/AMR.1004-1005.253
关键词:
摘要: A novel flame retardant additive, DOPO-based polymeric phosphate (PFR-D), which simultaneously contained phosphorus and sulfur, was synthesized from 9,10-dihyro-9-oxa-10-phosphaphnanthrene-10-oxide (DOPO), POCl3 bisphenol S. And the structure of PFR-D has been characterized by 1H-NMR, 31P-NMR FT-IR. used as additive in polycarbonate/acrylonitrile-butadiene-styrene alloy (PC/ABS). The UL94 V-0 rating achieved addition 5-7% PC/ABS, LOI reached 27.5%. thermal degradation polymers with it investigated TGA, results showed that apparently changed pyrolysis pathways PC/ABS. TGA curves indicated effect attributed to promoting char yield involving polymer charring.
sci-hub.se 参考文章(8)
Marie-Claire Despinasse, Bernhard Schartel, Influence of the structure of aryl phosphates on the flame retardancy of polycarbonate/acrylonitrile–butadiene–styrene Polymer Degradation and Stability. ,vol. 97, pp. 2571- 2580 ,(2012) , 10.1016/J.POLYMDEGRADSTAB.2012.07.005
Sergei V Levchik, Edward D Weil, Overview of recent developments in the flame retardancy of polycarbonates Polymer International. ,vol. 54, pp. 981- 998 ,(2005) , 10.1002/PI.1806
Sergei V Levchik, Edward D Weil, New developments in flame retardancy of styrene thermoplastics and foams Polymer International. ,vol. 57, pp. 431- 448 ,(2008) , 10.1002/PI.2282
Yu-Long Chang, Yu-Zhong Wang, Da-Ming Ban, Bing Yang, Guo-Ming Zhao, A Novel Phosphorus‐Containing Polymer as a Highly Effective Flame Retardant Macromolecular Materials and Engineering. ,vol. 289, pp. 703- 707 ,(2004) , 10.1002/MAME.200400064
John R Ebdon, Dennis Price, Barry J Hunt, Paul Joseph, Fengge Gao, G.John Milnes, Laurie K Cunliffe, Flame retardance in some polystyrenes and poly(methyl methacrylate)s with covalently bound phosphorus-containing groups: initial screening experiments and some laser pyrolysis mechanistic studies Polymer Degradation and Stability. ,vol. 69, pp. 267- 277 ,(2000) , 10.1016/S0141-3910(00)00066-5
A.I Balabanovich, J Engelmann, Fire retardant and charring effect of poly(sulfonyldiphenylene phenylphosphonate) in poly(butylene terephthalate) Polymer Degradation and Stability. ,vol. 79, pp. 85- 92 ,(2003) , 10.1016/S0141-3910(02)00258-6
Jeng-Yueh Shieh, Chun-Shan Wang, Synthesis of novel flame retardant epoxy hardeners and properties of cured products Polymer. ,vol. 42, pp. 7617- 7625 ,(2001) , 10.1016/S0032-3861(01)00257-9
De-Yi Wang, Xin-Guo Ge, Yu-Zhong Wang, Chuan Wang, Ming-Hai Qu, Qian Zhou, A Novel Phosphorus-Containing Poly(ethylene terephthalate) Nanocomposite with Both Flame Retardancy and Anti-Dripping Effects Macromolecular Materials and Engineering. ,vol. 291, pp. 638- 645 ,(2006) , 10.1002/MAME.200600017