Novel green method of preparation of a poly (ethylene oxide)/graphene nanocomposite using organic salt assisted dispersion

作者: Siddheshwar B. Jagtap , Ramakant K. Kushwaha , Debdatta Ratna

DOI: 10.1039/C5RA01236H

关键词:

摘要: Nanocomposites of poly (ethylene oxide) (PEO) and graphene were made in aqueous solution using an organic salt containing a carboxylate ion carboxylic acid group. The cation corresponding to the interacts with π electron clouds through cation–π interaction promotes exfoliation sheets. group modifier forms H-bonds PEO thereby improves interfacial adhesion. effect number carbon atoms present on its dispersing ability was investigated. It observed that there exists optimum respect level dispersion related nanocomposites as examined by scanning microscopy (SEM) transmission (TEM). mechanical properties having various concentrations evaluated compared theoretical values Halpin–Tsai model. crystallization behavior upon incorporation modified studied temperature modulated differential colorimetry (MDSC) discussed well. process used here is green it does not require any toxic solvent or hazardous material for modification graphene.

参考文章(52)
Kinga Pielichowska, Krzysztof Pielichowski, Novel biodegradable form stable phase change materials: Blends of poly(ethylene oxide) and gelatinized potato starch Journal of Applied Polymer Science. ,vol. 116, pp. 1725- 1731 ,(2010) , 10.1002/APP.31615
Debdatta Ratna, Swapnil Divekar, Sivaraman Patchaiappan, Asit Baran Samui, Bikash Chandra Chakraborty, Poly(ethylene oxide)/clay nanocomposites for solid polymer electrolyte applications Polymer International. ,vol. 56, pp. 900- 904 ,(2007) , 10.1002/PI.2222
R. Baloji Naik, S.B. Jagtap, R.S. Naik, N.G. Malvankar, D. Ratna, Effect of non-ionic surfactants on thermomechanical properties of epoxy/multiwall carbon nanotubes composites Progress in Organic Coatings. ,vol. 77, pp. 1883- 1889 ,(2014) , 10.1016/J.PORGCOAT.2014.06.024
Shin-Yi Yang, Chen-Chi M. Ma, Chih-Chun Teng, Yen-Wei Huang, Shu-Hang Liao, Yuan-Li Huang, Hsi-Wen Tien, Tzong-Ming Lee, Kuo-Chan Chiou, Effect of functionalized carbon nanotubes on the thermal conductivity of epoxy composites Carbon. ,vol. 48, pp. 592- 603 ,(2010) , 10.1016/J.CARBON.2009.08.047
D. Ratna, S. Divekar, A.B. Samui, B.C. Chakraborty, A.K. Banthia, Poly(ethylene oxide)/clay nanocomposite: Thermomechanical properties and morphology Polymer. ,vol. 47, pp. 4068- 4074 ,(2006) , 10.1016/J.POLYMER.2006.02.040
Pingan Song, Zhenhu Cao, Yuanzheng Cai, Liping Zhao, Zhengping Fang, Shenyuan Fu, Fabrication of exfoliated graphene-based polypropylene nanocomposites with enhanced mechanical and thermal properties Polymer. ,vol. 52, pp. 4001- 4010 ,(2011) , 10.1016/J.POLYMER.2011.06.045
Fang Ji, Ya-Li Li, Jian-Min Feng, Dong Su, Yang-Yang Wen, Yan Feng, Feng Hou, Electrochemical performance of graphene nanosheets and ceramic composites as anodes for lithium batteries Journal of Materials Chemistry. ,vol. 19, pp. 9063- 9067 ,(2009) , 10.1039/B915838C
Girish Galgali, C. Ramesh, Ashish Lele, A rheological study on the kinetics of hybrid formation in polypropylene nanocomposites Macromolecules. ,vol. 34, pp. 852- 858 ,(2001) , 10.1021/MA000565F
Dale W. Schaefer, Ryan S. Justice, How Nano Are Nanocomposites Macromolecules. ,vol. 40, pp. 8501- 8517 ,(2007) , 10.1021/MA070356W
Siddheshwar B. Jagtap, Debdatta Ratna, Novel Method of Dispersion of Multiwalled Carbon Nanotubes in a Flexible Epoxy Matrix Journal of Applied Polymer Science. ,vol. 130, pp. 2610- 2618 ,(2013) , 10.1002/APP.39230