Isolation of Helminthosporol as a Natural Plant Growth Regulator and its Chemical Structure

作者: Saburo Tamura , Akira Sakurai , Kihei Kainuma , Makoto Takai

DOI: 10.1080/00021369.1963.10858176

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摘要: Helminthosporol was isolated as a natural plant growth-regulator produced by Helminthosporium sativum and its structure assigned I. Oxidation of I with chromium trioxide-pyridine complex gave helminthosporal (II). The glycol (III), obtained the reduction or II, yielded oxidation activated manganese dioxide. spontaneously changed into helminthosporic acid (IV), when former in organic solvent let to stand air.

参考文章(2)
P. de Mayo, E. Y. Spencer, Robert W. White, HELMINTHOSPORAL, THE TOXIN FROM HELMINTHOSPORIUM SATIVUM: I. ISOLATION AND CHARACTERIZATION Canadian Journal of Chemistry. ,vol. 39, pp. 1608- 1612 ,(1961) , 10.1139/V61-205
P. de Mayo, E. Y. Spencer, Robert W. White, The Constitution of Helminthosporal Journal of the American Chemical Society. ,vol. 84, pp. 494- 495 ,(1962) , 10.1021/JA00862A037