Complementary ligands direct the formation of a calix[8]arene-supported ferromagnetic MnIVMnIII dimer

作者: Ross McLellan , Stephanie M. Taylor , Ruaraidh D. McIntosh , Euan K. Brechin , Scott J. Dalgarno

DOI: 10.1039/C3DT50294E

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摘要: A combination of complementary ligands, p-tert-butylcalix[8]arene (TBC[8]) and phenyl salicylaldoxime (Ph-saoH2) have been utilised in the facile synthesis a MnIIIMnIV dimer. Magnetic measurements reveal ferromagnetic exchange between two metal ions.

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