Highly efficient and stable MoP-RGO nanoparticles as electrocatalysts for hydrogen evolution

作者: Zexing Wu , Jie Wang , Jing Zhu , Junpo Guo , Weiping Xiao

DOI: 10.1016/J.ELECTACTA.2017.02.146

关键词:

摘要: Abstract Electrochemical splitting of water to obtain hydrogen plays a vital role in high energy density devices, especially for fuel cells. In this work, reduced graphene oxide supported molybdenum phosphide nanoparticles (MoP-RGO) were prepared via facile solvothermal reaction followed by high-temperature phosphating treatment. The electrochemical measurement results indicate that the MoP-RGO nanocomposite obtained at 900 °C exhibits excellent electrocatalytic activity evolution (HER) with overpotentials 117 mV and 150 mV current 10 mA cm −2 acid alkaline media, respectively. Furthermore, instability catalyst basic medium was systemically investigated. This work provides strategy synthesis cost-effective carbon metal as HER electrocatalyst.

参考文章(58)
Yao Wang, Yao Nie, Wei Ding, SG Chen, Kun Xiong, XQ Qi, Yun Zhang, Jun Wang, ZD Wei, None, Unification of catalytic oxygen reduction and hydrogen evolution reactions: highly dispersive Co nanoparticles encapsulated inside Co and nitrogen co-doped carbon. Chemical Communications. ,vol. 51, pp. 8942- 8945 ,(2015) , 10.1039/C5CC02400E
Ping Liu, José A. Rodriguez, Catalysts for hydrogen evolution from the [NiFe] hydrogenase to the Ni2P(001) surface: the importance of ensemble effect. Journal of the American Chemical Society. ,vol. 127, pp. 14871- 14878 ,(2005) , 10.1021/JA0540019
Zhong-Shuai Wu, Shubin Yang, Yi Sun, Khaled Parvez, Xinliang Feng, Klaus Müllen, 3D Nitrogen-Doped Graphene Aerogel-Supported Fe3O4 Nanoparticles as Efficient Electrocatalysts for the Oxygen Reduction Reaction Journal of the American Chemical Society. ,vol. 134, pp. 9082- 9085 ,(2012) , 10.1021/JA3030565
Wei Cui, Qian Liu, Zhicai Xing, Abdullah M Asiri, Khalid A Alamry, Xuping Sun, None, MoP nanosheets supported on biomass-derived carbon flake: One-step facile preparation and application as a novel high-active electrocatalyst toward hydrogen evolution reaction Applied Catalysis B-environmental. ,vol. 164, pp. 144- 150 ,(2015) , 10.1016/J.APCATB.2014.09.016
Duck Hyun Youn, Suenghoon Han, Jae Young Kim, Jae Yul Kim, Hunmin Park, Sun Hee Choi, Jae Sung Lee, Highly active and stable hydrogen evolution electrocatalysts based on molybdenum compounds on carbon nanotube-graphene hybrid support. ACS Nano. ,vol. 8, pp. 5164- 5173 ,(2014) , 10.1021/NN5012144
Sreekuttan M. Unni, Siddheshwar N. Bhange, Rajith Illathvalappil, Nisha Mutneja, Kasinath R. Patil, Sreekumar Kurungot, Nitrogen-induced surface area and conductivity modulation of carbon nanohorn and its function as an efficient metal-free oxygen reduction electrocatalyst for anion-exchange membrane fuel cells. Small. ,vol. 11, pp. 352- 360 ,(2015) , 10.1002/SMLL.201303892
Jinle Shi, Zonghua Pu, Qian Liu, Abdullah M Asiri, Jianming Hu, Xuping Sun, None, Tungsten nitride nanorods array grown on carbon cloth as an efficient hydrogen evolution cathode at all pH values Electrochimica Acta. ,vol. 154, pp. 345- 351 ,(2015) , 10.1016/J.ELECTACTA.2014.12.096
Hao Bin Wu, Bao Yu Xia, Le Yu, Xin-Yao Yu, Xiong Wen Lou, Porous molybdenum carbide nano-octahedrons synthesized via confined carburization in metal-organic frameworks for efficient hydrogen production Nature Communications. ,vol. 6, pp. 6512- 6512 ,(2015) , 10.1038/NCOMMS7512
S. Ted Oyama, Travis Gott, Haiyan Zhao, Yong-Kul Lee, Transition metal phosphide hydroprocessing catalysts: A review Catalysis Today. ,vol. 143, pp. 94- 107 ,(2009) , 10.1016/J.CATTOD.2008.09.019