Modified polymers prepared with lanthanide-based catalysts

作者: Takuo Sone , Koji Masaki , Koichi Morita , Yoichi Ozawa , Tatsuo Fujimaki

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摘要: A method for preparing a functionalized polymer comprising the steps of pseudo-living by polymerizing conjugated diene monomer with lanthanide-based catalyst, and reacting at least one functionalizing agent defined formula (I) where is substituent that will undergo an addition reaction polymer, R1 divalent organic group, R2 monovalent each R4, which may be same or different, group -OR5 R5 proviso A, R?1, R2, R5? are substituents not protonate polymer. Also, vulcanizable composition containing

参考文章(39)
Mitsuhiko Sakakibara, Fumio Tsutsumi, Masao Yoshizawa, Iwakazu Hattori, Preparation of conjugated diene polymers modified with an organo-tin or germanium halide ,(1989)
Gerd Sylvester, Josef Witte, Bernd Stollfuss, Process and catalyst for the preparation of syndiotactic 1,2-polybutadiene ,(1986)
Hiroshi Akema, Iwakazu Hattori, Takuo Sone, Kouichirou Tani, Ryouji Tanaka, Atsushi Nakayama, Modified conjugated diene polymer and method of producing the same and rubber composition ,(2000)
William L. Hergenrother, Thomas J. Lynch, James Oziomek, Hideo Takeichi, David F. Lawson, Composition of cyclic amine-initiated elastomers and amorphous silica and process for the production thereof ,(1998)
M Throckmorton, R Mournighan, Diolefin polymerization catalyst composition ,(1971)