Carbon nanotube sheet as a microporous layer for proton exchange membrane fuel cells

作者: Taehyun Park , Youngjin Jeong , Hyeonjun Song , Hyeok Kim , Dasol Kim

DOI: 10.1016/J.ENERGY.2021.120459

关键词:

摘要: Abstract A multi-walled carbon nanotube (CNT) sheet was employed and investigated as a microporous layer (MPL) of proton exchange membrane fuel cell (PEMFC). The CNT synthesized via floating catalyst chemical vapor deposition method. MPLs with the thickness 15, 30, 100 μm were prepared compared commercial carbon-black MPL. As result, it found that PEMFC 15-μm-thick MPL showed high electrochemical performance, outtopped conventional PEMFC. increased peak power density by 50.9% in air-supplied cathode 20.9% pure oxygen-supplied to Through impedance analyses, effectively decreased charge transfer resistance, which is attributed improved reaction kinetics mass transport through

参考文章(52)
Zhiyong Xie, Guofen Chen, Xiao Yu, Ming Hou, Zhigang Shao, Shaojing Hong, Cong Mu, Carbon nanotubes grown in situ on carbon paper as a microporous layer for proton exchange membrane fuel cells International Journal of Hydrogen Energy. ,vol. 40, pp. 8958- 8965 ,(2015) , 10.1016/J.IJHYDENE.2015.04.129
Ludovic Dumée, Vincent Germain, Kallista Sears, Jürg Schütz, Niall Finn, Mikel Duke, Sophie Cerneaux, David Cornu, Stephen Gray, Enhanced durability and hydrophobicity of carbon nanotube bucky paper membranes in membrane distillation Journal of Membrane Science. ,vol. 376, pp. 241- 246 ,(2011) , 10.1016/J.MEMSCI.2011.04.024
Q.-H. Yang, H.-M. Cheng, Carbon nanotubes: Surface, porosity, and related applications Carbon Nanotechnology#R##N#Recent Developments in Chemistry, Physics, Materials Science and Device Applications. pp. 323- 359 ,(2006) , 10.1016/B978-044451855-2/50015-2
I.S. Hussaini, C.Y. Wang, Measurement of relative permeability of fuel cell diffusion media Journal of Power Sources. ,vol. 195, pp. 3830- 3840 ,(2010) , 10.1016/J.JPOWSOUR.2009.12.105
Tatsumi Kitahara, Toshiaki Konomi, Hironori Nakajima, Microporous layer coated gas diffusion layers for enhanced performance of polymer electrolyte fuel cells Journal of Power Sources. ,vol. 195, pp. 2202- 2211 ,(2010) , 10.1016/J.JPOWSOUR.2009.10.089
Junhyun Cho, Hwanyeong Oh, Jaeman Park, Kyoungdoug Min, Eunsook Lee, Jy-Young Jyoung, Effect of the micro porous layer design on the dynamic performance of a proton exchange membrane fuel cell International Journal of Hydrogen Energy. ,vol. 39, pp. 459- 468 ,(2014) , 10.1016/J.IJHYDENE.2013.10.041
S. Slade, S. A. Campbell, T. R. Ralph, F. C. Walsh, Ionic Conductivity of an Extruded Nafion 1100 EW Series of Membranes Journal of The Electrochemical Society. ,vol. 149, ,(2002) , 10.1149/1.1517281
Jer-Huan Jang, Wei-Mon Yan, Chinh-Chang Shih, Effects of the gas diffusion-layer parameters on cell performance of PEM fuel cells Journal of Power Sources. ,vol. 161, pp. 323- 332 ,(2006) , 10.1016/J.JPOWSOUR.2006.03.089
K.K. Poornesh, Chongdu Cho, Do-Young Kim, Yongsug Tak, Effect of gas-diffusion electrode material heterogeneity on the structural integrity of polymer electrolyte fuel cell Energy. ,vol. 35, pp. 5241- 5249 ,(2010) , 10.1016/J.ENERGY.2010.07.041