The Flash Photolysis of Phosphine

作者:

DOI: 10.1098/RSPA.1961.0097

关键词:

摘要: The equation representing the decomposition of phosphine by flash photolysis is shown to be PH 3 → P red + 3/2H 2 . phosphorus produced in form small particles which remain suspended gas phase for several minutes provided that total pressure high enough. variation with time spectra , and has been studied secondary reactions consequent upon are homogeneous. a vibrationally excited state at room temperature, transitions involving levels up v9 = 7 being observed. A mechanism production proposed.

参考文章(7)
L. S. Nelson, D. A. Ramsay, Flash Photolysis Experiments with a Sapphire Flash Lamp The Journal of Chemical Physics. ,vol. 25, pp. 372- 372 ,(1956) , 10.1063/1.1742909
David. Sinclair, Victor K. La Mer, Light Scattering as a Measure of Particle Size in Aerosols. The Production of Monodisperse Aerosols. Chemical Reviews. ,vol. 44, pp. 245- 267 ,(1949) , 10.1021/CR60138A001
Gerhard Herzberg, Bandenspektrum, Prädissoziation und Struktur des P2-Moleküls Annalen der Physik. ,vol. 407, pp. 677- 706 ,(1932) , 10.1002/ANDP.19324070605
Cyril Norman Hinshelwood, Bryan Topley, XLVII.—The unimolecular decomposition of phosphine Journal of The Chemical Society, Transactions. ,vol. 125, pp. 393- 406 ,(1924) , 10.1039/CT9242500393
N. N. Semenov, Henry Wise, Michel Boudart, Some problems in chemical kinetics and reactivity ,(1958)
A. Jakowlewa, Fluoreszenz und Absorption des Phosphordampfes European Physical Journal. ,vol. 69, pp. 548- 564 ,(1931) , 10.1007/BF01403570