Polymerization of Allylhalides, Butadienes and Acetylenes Induced by Active Uranium Powder

作者: C. C. Chang , C. P. Cheng , C. T. Chang

DOI: 10.1002/JCCS.198500049

关键词:

摘要: Allylhalides, butadienes and acetylenes were reacted with an active uranium powder which was prepared via electrolytic amalgamation. The reactions conducted under a mild condition brought forth series of oligomers polymers. structures characterized by means IR NMR spectroscopy. Possible reaction routes are suggested.

参考文章(22)
P.L. Timms, Low Temperature Condensation of High Temperature Species as a Synthetic Method Advances in Inorganic Chemistry and Radiochemistry. ,vol. 14, pp. 121- 171 ,(1972) , 10.1016/S0065-2792(08)60006-0
G.N. Schrauzer, Some Advances in the Organometallic Chemistry of Nickel Advances in Organometallic Chemistry. ,vol. 2, pp. 1- 48 ,(1965) , 10.1016/S0065-3055(08)60076-3
Sei Otsuka, Akira Nakamura, Acetylene and Allene Complexes: Their Implication in Homogeneous Catalysis Advances in Organometallic Chemistry. ,vol. 14, pp. 245- 283 ,(1976) , 10.1016/S0065-3055(08)60654-1
N. K. Sung-Yu, F. F. Hsu, C. C. Chang, G. R. Her, C. T. Chang, New route for the synthesis of tricyclopentadienyluranium halides Inorganic Chemistry. ,vol. 12, pp. 2727- 2728 ,(1981) , 10.1021/IC50222A070
Yasuyuki Tanaka, Yasumasa Takeuchi, Masamichi Kobayashi, Hiroyuki Tadokoro, Characterization of diene polymers. I. Infrared and NMR studies: Nonadditive behavior of characteristic infrared bands Journal of Polymer Science Part A-2: Polymer Physics. ,vol. 9, pp. 43- 57 ,(1971) , 10.1002/POL.1971.160090104
Chung-Cheng Chang, Studies of the Fischer-Tropsch process on uranium catalysts Inorganica Chimica Acta. ,vol. 94, pp. 259- 262 ,(1984) , 10.1016/S0020-1693(00)87453-8
E. L. Muetterties, Metal Clusters in Catalysis III. - Clusters as Models for Chemisorption Processes and Heterogeneous Catalysis Bulletin des Sociétés Chimiques Belges. ,vol. 84, pp. 959- 986 ,(2010) , 10.1002/BSCB.19750841006
L. S. MERIWETHER, E. C. COLTHUP, G. W. KENNERLY, R. N. REUSCH, The Polymerization of Acetylenes by Nickel-Carbonyl-Phosphine Complexes. I. Scope of the Reaction1a Journal of Organic Chemistry. ,vol. 26, pp. 5155- 5163 ,(1961) , 10.1021/JO01070A091
H. C. Lee, L. C. Wang, H. H. Hung, C. T. Chang, Electrolytic amalgamation of uranium using an ion exchange membrane Journal of The Chemical Society, Chemical Communications. ,(1975) , 10.1039/C3975000124A
J. C. Kauer, H. E. Simmons, Tetramers of acetylenedicarboxylic esters Journal of Organic Chemistry. ,vol. 33, pp. 2720- 2726 ,(1968) , 10.1021/JO01271A023