Dibenzo[b,def]chrysene Derivatives: Solution-Processable Small Molecules that Deliver High Power-Conversion Efficiencies in Bulk Heterojunction Solar Cells

作者: Kevin N Winzenberg , Peter Kemppinen , Giovanni Fanchini , Mark Bown , Gavin E Collis

DOI: 10.1021/CM9028337

关键词:

摘要: Soluble, electroactive derivatives based upon dibenzo[b,def]chrysene are introduced. These compounds do not chemically react with fullerenes, enabling the preparation of solution-processed solar cells on small molecule blends. Device power conversion efficiencies 2.25% described and a correlation between processing conditions, film morphology, device is demonstrated.

参考文章(19)
Nikos Kopidakis, William J. Mitchell, Jao van de Lagemaat, David S. Ginley, Garry Rumbles, Sean E. Shaheen, William L. Rance, Bulk heterojunction organic photovoltaic devices based on phenyl-cored thiophene dendrimers Applied Physics Letters. ,vol. 89, pp. 103524- ,(2006) , 10.1063/1.2337859
Barry C. Thompson, Jean M. J. Fréchet, Polymer–Fullerene Composite Solar Cells Angewandte Chemie. ,vol. 47, pp. 58- 77 ,(2008) , 10.1002/ANIE.200702506
Jae Kwan Lee, Wan Li Ma, Christoph J. Brabec, Jonathan Yuen, Ji Sun Moon, Jin Young Kim, Kwanghee Lee, Guillermo C. Bazan, Alan J. Heeger, Processing Additives for Improved Efficiency from Bulk Heterojunction Solar Cells Journal of the American Chemical Society. ,vol. 130, pp. 3619- 3623 ,(2008) , 10.1021/JA710079W
Peter Peumans, Soichi Uchida, Stephen R. Forrest, Efficient bulk heterojunction photovoltaic cells using small-molecular-weight organic thin films Nature. ,vol. 425, pp. 158- 162 ,(2003) , 10.1038/NATURE01949
W. Ma, C. Yang, X. Gong, K. Lee, A. J. Heeger, Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology Advanced Functional Materials. ,vol. 15, pp. 1617- 1622 ,(2005) , 10.1002/ADFM.200500211
John E. Anthony, The larger acenes: versatile organic semiconductors. Angewandte Chemie. ,vol. 47, pp. 452- 483 ,(2008) , 10.1002/ANIE.200604045
Fabio Silvestri, Michael D. Irwin, Luca Beverina, Antonio Facchetti, Giorgio A. Pagani, Tobin J. Marks, Efficient squaraine-based solution processable bulk-heterojunction solar cells. Journal of the American Chemical Society. ,vol. 130, pp. 17640- 17641 ,(2008) , 10.1021/JA8067879
Nils M. Kronenberg, Manuela Deppisch, Frank Würthner, Hans W. A. Lademann, Kaja Deing, Klaus Meerholz, Bulk heterojunction organic solar cells based on merocyanine colorants Chemical Communications. pp. 6489- 6491 ,(2008) , 10.1039/B813341G
Lukas Schmidt-Mende, A Fechtenkotter, K Mullen, Ellen Moons, Richard H Friend, J Devin MacKenzie, Self-Organized Discotic Liquid Crystals for High-Efficiency Organic Photovoltaics Science. ,vol. 293, pp. 1119- 1122 ,(2001) , 10.1126/SCIENCE.293.5532.1119
M. C. Scharber, D. Mühlbacher, M. Koppe, P. Denk, C. Waldauf, A. J. Heeger, C. J. Brabec, Design Rules for Donors in Bulk‐Heterojunction Solar Cells—Towards 10 % Energy‐Conversion Efficiency Advanced Materials. ,vol. 20, pp. 579- 583 ,(2006) , 10.1002/ADMA.200501717