Photocatalytic degradation of organic dye by sol-gel-derived gallium-doped anatase titanium oxide nanoparticles for environmental remediation

作者: Arghya Narayan Banerjee , Sang Woo Joo , Bong-Ki Min

DOI: 10.1155/2012/201492

关键词:

摘要: Photocatalytic degradation of toxic organic chemicals is considered to be the most efficient green method for surface water treatment. We have reported sol-gel synthesis Gadoped anatase TiO2 nanoparticles and photocatalytic oxidation dye into nontoxic inorganic products under UV irradiation. Photodegradation experiments show very good activity Ga-doped with almost 90% efficiency within 3 hrs irradiation, which faster than undoped samples. Doping levels created bandgap act as trapping centers suppress photogenerated electron-hole recombination proper timely utilization charge carriers generation strong oxidizing radicals degrade dye. found follow pseudo-first-order kinetics apparent 1st order rate constant around 1.3 × 10-2 min-1. The cost-effective, sol-gel-derived :Ga can used efficiently light-assisted molecules in environmental remediation.

参考文章(59)
Toshihiro Okajima, Tomoyuki Yamamoto, Masahiro Kunisu, Satoru Yoshioka, Isao Tanaka, Norimasa Umesaki, Dilute Ga dopant in TiO2 by X-ray absorption near-edge structure Japanese Journal of Applied Physics. ,vol. 45, pp. 7028- 7031 ,(2006) , 10.1143/JJAP.45.7028
Wang Peng-Weio, Song Yi-Pu, Zhang Xin-Zheng, Xu Jun, Yu Da-Peng, None, Transformation from β-Ga2O3 to GaN Nanowires via Nitridation Chinese Physics Letters. ,vol. 25, pp. 1038- 1041 ,(2008) , 10.1088/0256-307X/25/3/063
Dana Dvoranová, Vlasta Brezová, Milan Mazúr, Mounir A. Malati, Investigations of metal-doped titanium dioxide photocatalysts Applied Catalysis B-environmental. ,vol. 37, pp. 91- 105 ,(2002) , 10.1016/S0926-3373(01)00335-6
Cathy McCullagh, Jeanette M. C. Robertson, Detlef W. Bahnemann, Peter K. J. Robertson, The application of TiO2 photocatalysis for disinfection of water contaminated with pathogenic micro-organisms: a review Research on Chemical Intermediates. ,vol. 33, pp. 359- 375 ,(2007) , 10.1163/156856707779238775
Bernard Dennis Cullity, Elements of X-ray diffraction ,(1956)
K. Wilke, H.D. Breuer, The influence of transition metal doping on the physical and photocatalytic properties of titania Journal of Photochemistry and Photobiology A-chemistry. ,vol. 121, pp. 49- 53 ,(1999) , 10.1016/S1010-6030(98)00452-3
Yanfang Shen, Tianying Xiong, Tiefan Li, Ke Yang, Tungsten and nitrogen co-doped TiO2 nano-powders with strong visible light response Applied Catalysis B-environmental. ,vol. 83, pp. 177- 185 ,(2008) , 10.1016/J.APCATB.2008.01.037
Brian O'Regan, Michael Grätzel, A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films Nature. ,vol. 353, pp. 737- 740 ,(1991) , 10.1038/353737A0
Shuang Song, Cheng Wang, Fangyue Hong, Zhiqiao He, Qiaolan Cai, Jianmeng Chen, Gallium- and iodine-co-doped titanium dioxide for photocatalytic degradation of 2-chlorophenol in aqueous solution: Role of gallium Applied Surface Science. ,vol. 257, pp. 3427- 3432 ,(2011) , 10.1016/J.APSUSC.2010.11.040
Ulrike Diebold, The surface science of titanium dioxide Surface Science Reports. ,vol. 48, pp. 53- 229 ,(2003) , 10.1016/S0167-5729(02)00100-0