Attempts to Fill the Gap Between Enzymatic, Homogeneous, and Heterogeneous Catalysis

摘要: Abstract Bio‐inspired and single site metal complex catalysts have been discussed to direct towards a rational design of solid heterogeneous catalysts. When concepts derived from catalytic antibodies, molecular imprinting recognition, isolation modification by appropriate ligands are combined, with new techniques prepare, tailor made materials, can be prepared that improve reaction rate selectivity increasing the concentration activation reactants in vicinity active sites, stabilizing transition states or intermediate products. It is also shown enzymatic, homogeneous hetergeneous combined perform “one‐pot” cascade reactions.