BODIPY modified g-C3N4 as a highly efficient photocatalyst for degradation of Rhodamine B under visible light irradiation

作者: De-Gao Wang , Pengfei Tan , Huan Wang , Min Song , Jun Pan

DOI: 10.1016/J.JSSC.2018.08.002

关键词:

摘要: Abstract Developing new energy resource as well efficient treatment strategies to solve the crisis and organic pollutants problems is of crucial importance. Due medium band gap highly thermal stability, doped or chemically functionallized graphitic carbon nitride (g-C3N4) has been envisioned promising photocatalysts in processing pollutants. In this work, we use 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) modified g-C3N4 degrade Rhodamine B (RhB) under visible light irradiation (λ ≥ 420 nm). When weight ratio BODIPY reaches 0.6% (CN-0.6), photocatalytic performance nearly 3.5 times fast than that without modification (CN-0). Enhanced absorption depressed electron-hole recombination rate may take responsibilities for enhanced photocalytic performance. A possible mechanism responsible process proposed. Our work might provide a strategy develop valid with broad absorption.

参考文章(37)
Xiangqian Fan, Lingxia Zhang, Min Wang, Weimin Huang, Yajun Zhou, Mengli Li, Ruolin Cheng, Jianlin Shi, Constructing carbon-nitride-based copolymers via Schiff base chemistry for visible-light photocatalytic hydrogen evolution Applied Catalysis B-environmental. ,vol. 182, pp. 68- 73 ,(2016) , 10.1016/J.APCATB.2015.09.006
Rajeev Jain, Megha Mathur, Shalini Sikarwar, Alok Mittal, Removal of the hazardous dye rhodamine B through photocatalytic and adsorption treatments Journal of Environmental Management. ,vol. 85, pp. 956- 964 ,(2007) , 10.1016/J.JENVMAN.2006.11.002
Yao Zheng, Jian Liu, Ji Liang, Mietek Jaroniec, Shi Zhang Qiao, Graphitic carbon nitride materials: controllable synthesis and applications in fuel cells and photocatalysis Energy and Environmental Science. ,vol. 5, pp. 6717- 6731 ,(2012) , 10.1039/C2EE03479D
Aurore Loudet, Kevin Burgess, BODIPY dyes and their derivatives: syntheses and spectroscopic properties. Chemical Reviews. ,vol. 107, pp. 4891- 4932 ,(2007) , 10.1021/CR078381N
Wingkei Ho, Zizhong Zhang, Wei Lin, Shuping Huang, Xianwen Zhang, Xuxu Wang, Yu Huang, Copolymerization with 2,4,6-triaminopyrimidine for the rolling-up the layer structure, tunable electronic properties, and photocatalysis of g-C3N4. ACS Applied Materials & Interfaces. ,vol. 7, pp. 5497- 5505 ,(2015) , 10.1021/AM509213X
K.Y. Foo, B.H. Hameed, Decontamination of textile wastewater via TiO2/activated carbon composite materials Advances in Colloid and Interface Science. ,vol. 159, pp. 130- 143 ,(2010) , 10.1016/J.CIS.2010.06.002
Junjiang Zhu, Ping Xiao, Hailong Li, Sónia A. C. Carabineiro, Graphitic Carbon Nitride: Synthesis, Properties, and Applications in Catalysis ACS Applied Materials & Interfaces. ,vol. 6, pp. 16449- 16465 ,(2014) , 10.1021/AM502925J
David James Martin, Kaipei Qiu, Stephen Andrew Shevlin, Albertus Denny Handoko, Xiaowei Chen, Zhengxiao Guo, Junwang Tang, Highly efficient photocatalytic H₂ evolution from water using visible light and structure-controlled graphitic carbon nitride. Angewandte Chemie. ,vol. 53, pp. 9240- 9245 ,(2014) , 10.1002/ANIE.201403375
Shaowen Cao, Jingxiang Low, Jiaguo Yu, Mietek Jaroniec, Polymeric Photocatalysts Based on Graphitic Carbon Nitride Advanced Materials. ,vol. 27, pp. 2150- 2176 ,(2015) , 10.1002/ADMA.201500033
Xi Chen, Banghong Zhou, Shuanglei Yang, Hanshuo Wu, Yuxin Wu, Laidi Wu, Jun Pan, Xiang Xiong, In situ construction of an SnO2/g-C3N4 heterojunction for enhanced visible-light photocatalytic activity RSC Advances. ,vol. 5, pp. 68953- 68963 ,(2015) , 10.1039/C5RA11801H