Interaction of some biomolecules with π- and σ-acceptors
作者： Vinod Singh , Ram Sahai
DOI: 10.1007/BF00816528
关键词:
摘要: Electrical conductance, refractometric and differential techniques have been used to study the charge-transfer interaction of some biomolecules with chloranil iodine, their ion-pair separation. A mechanism transformation outer complex inner has suggested. The coexistence intimate solvent-separated ion-pairs in equilibrium binary mixtures dioxan—THF is indicated for these complexes. constant (K) solvation number (n) equilibria;AAI+, I 3 − +nTHF\(\mathop \rightleftharpoons \limits^K\)AAI+//I ;GBI+, ;GBI+//I , calculated it was found that a singleTHF molecule managed intercalate between cation anion.
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sci-hub.se 参考文章(11)
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