Effect of Water on the Partial Oxidation of Propane to Acrylic and Acetic Acids on Mo-V-Sb-Nb Mixed Oxides
作者： Ekaterina K. Novakova , Eric G. Derouane , Jacques C. Védrine
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摘要: It is shown that the major effect of water in oxidation propane to acrylic and acetic acids on Mo1V0.3Sb0.25Nb0.08On catalysts stabilise active sites increase rates formation both acids. The usual favoring desorption products considered be secondary.
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J. Barrault, C. Batiot, L. Magaud, M. Ganne, Selective oxidation of propane into oxygenated compounds over promoted nickel-molybdenum catalysts Studies in Surface Science and Catalysis. ,vol. 110, pp. 375- 382 ,(1997) , 10.1016/S0167-2991(97)80998-6
Roberto Catani, Gabriele Centi, Ferruccio Trifiro, Robert K. Grasselli, Kinetics and reaction network in propane ammoxidation to acrylonitrile on vanadium-antimony-aluminum based mixed oxides Industrial & Engineering Chemistry Research. ,vol. 31, pp. 107- 119 ,(1992) , 10.1021/IE00001A016
David L. Stern, Robert K. Grasselli, Reaction network and kinetics of propane oxydehydrogenation over nickel cobalt molybdate Journal of Catalysis. ,vol. 167, pp. 560- 569 ,(1997) , 10.1006/JCAT.1997.1569
Mamoru Ai, Oxidation of propane over V2O5–P2O5-based catalysts at relatively low temperatures Catalysis Today. ,vol. 42, pp. 297- 301 ,(1998) , 10.1016/S0920-5861(98)00105-9
M AI, Oxidation of propane to acrylic acid on V2O5&P2O5-based catalysts Journal of Catalysis. ,vol. 101, pp. 389- 395 ,(1986) , 10.1016/0021-9517(86)90266-6
Jean-Claude Volta, Dynamic processes on vanadium phosphorous oxides for selective alkane oxidation Catalysis Today. ,vol. 32, pp. 29- 36 ,(1996) , 10.1016/S0920-5861(96)00073-9
Jacques C. Vedrine, Jean Marc M. Millet, Jean-Claude Volta, Molecular description of active sites in oxidation reactions: Acid-base and redox properties, and role of water Catalysis Today. ,vol. 32, pp. 115- 123 ,(1996) , 10.1016/S0920-5861(96)00185-X
A Kaddouri, C Mazzocchia, E Tempesti, The synthesis of acrolein and acrylic acid by direct propane oxidation with Ni-Mo-Te-P-O catalysts Applied Catalysis A-general. ,vol. 180, pp. 271- 275 ,(1999) , 10.1016/S0926-860X(98)00352-4