Pt-[NCN] Pincer Conducting Metallopolymers That Display Redox-Attenuated Metal−Ligand Interactions

作者: Kristen M. Milum , Young Nam Kim , Bradley J. Holliday

DOI: 10.1021/CM100762S

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摘要: A series of new Pt-pincer complexes with electropolymerizable substituents has been prepared and studied. Our approach utilizes metal synthetically incorporated into a conducting polymer, taking advantage it as redox-active ligand. The design, synthesis, characterization, redox-attenuated properties these monomers corresponding metallopolymers are presented.

参考文章(15)
Sarah E. Angell, Cerrie W. Rogers, Yan Zhang, Michael O. Wolf, Wayne E. Jones, Hemilabile coordination complexes for sensing applications Coordination Chemistry Reviews. ,vol. 250, pp. 1829- 1841 ,(2006) , 10.1016/J.CCR.2006.03.023
Michael O Wolf, None, Transition‐Metal–Polythiophene Hybrid Materials Advanced Materials. ,vol. 13, pp. 545- 553 ,(2001) , 10.1002/1521-4095(200104)13:8<545::AID-ADMA545>3.0.CO;2-3
Jean Luc Bredas, G. Bryan Street, Polarons, bipolarons, and solitons in conducting polymers Accounts of Chemical Research. ,vol. 18, pp. 309- 315 ,(1985) , 10.1021/AR00118A005
Elena Poverenov, Mark Gandelman, Linda J. W. Shimon, Haim Rozenberg, Yehoshoa Ben-David, David Milstein, Pincer “Hemilabile” Effect. PCN Platinum(II) Complexes with Different Amine “Arm Length” Organometallics. ,vol. 24, pp. 1082- 1090 ,(2005) , 10.1021/OM049182M
Changsik Song, Timothy M. Swager, Highly Conductive Poly(phenylene thienylene)s: m-Phenylene Linkages Are Not Always Bad Macromolecules. ,vol. 38, pp. 4569- 4576 ,(2005) , 10.1021/MA0501702
Hershel Jude, Jeanette A. Krause Bauer, William B. Connick, Synthesis, structures, and emissive properties of platinum(II) complexes with a cyclometallating aryldiamine ligand. Inorganic Chemistry. ,vol. 41, pp. 2275- 2281 ,(2002) , 10.1021/IC0108991