Remote electrochemical biosensor for field monitoring of phenolic compounds

作者: Joseph Wang , Qiang Chen

DOI: 10.1016/0003-2670(95)00207-G

关键词:

摘要: A submersible probe for monitoring of phenolic compounds at large sample/instrument distances is described. specially designed device, comprising a tyrosinase enzyme electrode coupled to 50-ft long shielded cable (via environmentally sealed connectors), used. Challenges associated with the adaptation electrodes remote sensing are addressed. Variables relevant field operations explored and discussed. The combination biocatalytic recognition amperometric transduction offers highly selective measurements micromolar concentrations substrates in untreated river groundwater samples. concept seems suited other via judicious selection biorecognition element.

参考文章(8)
Julie. Wangsa, Mark A. Arnold, Fiber-optic biosensors based on the fluorometric detection of reduced nicotinamide adenine dinucleotide. Analytical Chemistry. ,vol. 60, pp. 1080- 1082 ,(1988) , 10.1021/AC00161A027
G. Rivas, V.M. Solis, Electrochemical determination of the kinetic parameters of mushroom tyrosinase Bioelectrochemistry and Bioenergetics. ,vol. 29, pp. 19- 28 ,(1992) , 10.1016/0302-4598(92)80050-Q
L. Campanella, T. Beone, M. P. Sammartino, M. Tomassetti, Determination of phenol in wastes and water using an enzyme sensor Analyst. ,vol. 118, pp. 979- 986 ,(1993) , 10.1039/AN9931800979
F. Ortega, J.L. Cuevas, J.I. Centenera, E. Domi´nguez, Liquid chromatographic separation of phenolic drugs using catalytic detection: comparison of an enzyme reactor and enzyme electrode. Journal of Pharmaceutical and Biomedical Analysis. ,vol. 10, pp. 789- 796 ,(1992) , 10.1016/0731-7085(91)80082-K
Serge Cosnier, Christophe Innocent, A new strategy for the construction of a tyrosinase-based amperometric phenol and o-diphenol sensor Bioelectrochemistry and Bioenergetics. ,vol. 31, pp. 147- 160 ,(1993) , 10.1016/0302-4598(93)80003-D
Richard J. Berman, Gary D. Christian, Lloyd W. Burgess, Measurement of sodium hydroxide concentration with a renewable reagent-based fiber-optic sensor Analytical Chemistry. ,vol. 62, pp. 2066- 2071 ,(1990) , 10.1021/AC00218A003
Joseph Wang, Lu Fang, David Lopez, Amperometric biosensor for phenols based on a tyrosinase–graphite–epoxy biocomposite Analyst. ,vol. 119, pp. 455- 458 ,(1994) , 10.1039/AN9941900455
Konrad Lerch, Neurospora tyrosinase: structural, spectroscopic and catalytic properties Molecular and Cellular Biochemistry. ,vol. 52, pp. 125- 138 ,(1983) , 10.1007/BF00224921