Infiltration of commercially available, anode supported SOFC’s via inkjet printing

作者: T. B. Mitchell-Williams , R. I. Tomov , S. A. Saadabadi , M. Krauz , P. V. Aravind

DOI: 10.1007/S40243-017-0096-2

关键词:

摘要: Commercially available anode supported solid oxide fuel cells (NiO-8YSZ/8YSZ/LSCF- 20 mm in diameter) were infiltrated with gadolinium doped ceria (CGO) using a scalable drop-on-demand inkjet printing process. Cells two different precursor solutions—water based or propionic acid based. The saturation limit of the 0.5 μm thick supports sintered at 1400 °C was found to be approximately 1wt%. No significant enhancement power output recorded practical voltage levels. Microstructural characterisation carried out after electrochemical performance testing high resolution scanning electron microscopy. This work demonstrates that despite feasibility achieving CGO nanoparticle infiltration into thick, commercial SOFC anodes simple, low-cost and industrially procedure other loss mechanisms dominant. Infiltration model symmetric ink demonstrated reductions polarisation resistance possible.

参考文章(29)
Muhammad Shirjeel Khan, Wandi Wahyudi, Seung-Bok Lee, Rak-Hyun Song, Jong-Won Lee, Tak-Hyoung Lim, Seok-Joo Park, Effect of various sintering inhibitors on the long term performance of Ni-YSZ anodes used for SOFCs International Journal of Hydrogen Energy. ,vol. 40, pp. 11968- 11975 ,(2015) , 10.1016/J.IJHYDENE.2015.04.145
S. P. S. Badwal, S. Giddey, C. Munnings, A. Kulkarni, Review of Progress in High Temperature Solid Oxide Fuel Cells ChemInform. ,vol. 46, ,(2014) , 10.1002/CHIN.201531316
Arnab Choudhury, H. Chandra, A. Arora, Application of solid oxide fuel cell technology for power generation—A review Renewable & Sustainable Energy Reviews. ,vol. 20, pp. 430- 442 ,(2013) , 10.1016/J.RSER.2012.11.031
T. Z. Sholklapper, H. Kurokawa, C. P. Jacobson, S. J. Visco, L. C. De Jonghe, Nanostructured Solid Oxide Fuel Cell Electrodes Nano Letters. ,vol. 7, pp. 2136- 2141 ,(2007) , 10.1021/NL071007I
Trine Klemensø, Karl Thydén, Ming Chen, Hsiang-Jen Wang, Stability of Ni–yttria stabilized zirconia anodes based on Ni-impregnation Journal of Power Sources. ,vol. 195, pp. 7295- 7301 ,(2010) , 10.1016/J.JPOWSOUR.2010.05.047
Zhangbo Liu, Dong Ding, Beibei Liu, Weiwei Guo, Wendong Wang, Changrong Xia, Effect of impregnation phases on the performance of Ni-based anodes for low temperature solid oxide fuel cells Journal of Power Sources. ,vol. 196, pp. 8561- 8567 ,(2011) , 10.1016/J.JPOWSOUR.2011.05.076
M Mosiadz, R I Tomov, S C Hopkins, G Martin, B Holzapfel, B A Glowacki, Inkjet printing of multiple Ce0.8Gd0.2O2 buffer layers on a Ni-5%W substrate Journal of Physics: Conference Series. ,vol. 234, pp. 022024- ,(2010) , 10.1088/1742-6596/234/2/022024
R. Barfod, A. Hagen, S. Ramousse, P. V. Hendriksen, M. Mogensen, Break down of losses in thin electrolyte SOFCs Fuel Cells. ,vol. 6, pp. 141- 145 ,(2006) , 10.1002/FUCE.200500113
Lutgard C. DeJonghe, Steven J. Visco, Michael C. Tucker, Grace Y. Lau, Craig P. Jacobson, Performance of metal-supported SOFCs with infiltrated electrodes Journal of Power Sources. ,vol. 171, pp. 477- 482 ,(2007) , 10.1016/J.JPOWSOUR.2007.06.076