The influence of reactant vibrational excitation on the O(3P) + O†3 bimolecular reaction rate

作者: Gary A. West , Ralph E. Weston , George W. Flynn

DOI: 10.1016/0009-2614(78)89008-3

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摘要: Atomic resonance fluorescence has been used to monitor the disappearance rate of oxygen atoms in presence vibrationally excited ozone produced by a pulsed CO2 laser. An upper limit determined for coefficient O(3P) + O†3 bimolecular reaction. Comparison with previously measured deactivation indicates that at most small fraction (<30%) relaxation is due laser enhanced

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