Comparative study of HTO diffusion on individual and coupled systems of compacted bentonite and fresh ordinary Portland cement paste

作者: Tomáš Rosendorf , Eva Hofmanová , Dušan Vopálka , Aleš Vetešník , Radek Červinka

DOI: 10.1016/J.APGEOCHEM.2018.08.006

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摘要: Abstract The radionuclide transport on the interface of compacted bentonite and cementitious materials has been rarely investigated. goal our project is to understand how processes at affect properties bentonite. paper describes methodology evaluation procedure applied HTO through-diffusion experiments bentonite/fresh hardened cement paste (coupled system). Under same experimental conditions, were performed individual compared in coupled system. To compare these two types experiments, samples saturated separately before start experiments. An original method modelling system was applied. effective diffusion coefficients both arrangements, coupled, found be a very good agreement. Based finding, prepared porous can considered applicable further planned studies interfaces. A less agreement, but still satisfactory, obtained for fresh paste.

参考文章(25)
David Savage, Jinsong Liu, Water/clay ratio, clay porosity models and impacts upon clay transformations Applied Clay Science. ,vol. 116, pp. 16- 22 ,(2015) , 10.1016/J.CLAY.2015.08.011
T. Melkior, E.C. Gaucher, C. Brouard, S. Yahiaoui, D. Thoby, Ch. Clinard, E. Ferrage, D. Guyonnet, C. Tournassat, D. Coelho, Na + and HTO diffusion in compacted bentonite: Effect of surface chemistry and related texture Journal of Hydrology. ,vol. 370, pp. 9- 20 ,(2009) , 10.1016/J.JHYDROL.2009.02.035
Andreas Jenni, Urs Mäder, Catherine Lerouge, Stéphane Gaboreau, B Schwyn, None, In situ interaction between different concretes and Opalinus Clay Physics and Chemistry of The Earth. ,vol. 70, pp. 71- 83 ,(2014) , 10.1016/J.PCE.2013.11.004
T Melkior, D Mourzagh, S Yahiaoui, D Thoby, J.C Alberto, C Brouard, N Michau, Diffusion of an alkaline fluid through clayey barriers and its effect on the diffusion properties of some chemical species Applied Clay Science. ,vol. 26, pp. 99- 107 ,(2004) , 10.1016/J.CLAY.2003.10.006
Takafumi Sugiyama, Yukikazu Tsuji, Use of a migration technique to study alteration of compacted sand–bentonite mixture in contact with concrete Physics and Chemistry of the Earth, Parts A/B/C. ,vol. 33, pp. S276- S284 ,(2008) , 10.1016/J.PCE.2008.10.057
S. Nakayama, Y. Sakamoto, T. Yamaguchi, M. Akai, T. Tanaka, T. Sato, Y. Iida, Dissolution of montmorillonite in compacted bentonite by highly alkaline aqueous solutions and diffusivity of hydroxide ions Applied Clay Science. ,vol. 27, pp. 53- 65 ,(2004) , 10.1016/J.CLAY.2003.12.023
Ola Karnland, Siv Olsson, Ulf Nilsson, Patrik Sellin, Experimentally determined swelling pressures and geochemical interactions of compacted Wyoming bentonite with highly alkaline solutions Physics and Chemistry of The Earth. ,vol. 32, pp. 275- 286 ,(2007) , 10.1016/J.PCE.2006.01.012
S. Motellier, I. Devol-Brown, S. Savoye, D. Thoby, J.-C. Alberto, Evaluation of tritiated water diffusion through the Toarcian clayey formation of the Tournemire experimental site (France) Journal of Contaminant Hydrology. ,vol. 94, pp. 99- 108 ,(2007) , 10.1016/J.JCONHYD.2007.05.012