Thermal and flow effects during adsorption in conventional, diluted and annular packed beds

作者: Witold Kwapinski , Karijm Salem , Dieter Mewes , Evangelos Tsotsas

DOI: 10.1016/J.CES.2010.04.017

关键词:

摘要: Previous investigations have shown a complex combination of thermal and flow effects during adsorption in highly loaded, narrow packed beds. Respective conditions were realized by packing relatively large zeolite particles tube (which causes wall channelling) adsorbing water vapour from air on the is exothermic). The present work extends investigation to novel column configurations with purposely altered heat generation flow—namely diluted beds, annular beds consisting coated particles. Experimental results obtained near infrared tomography are compared breakthrough experiments conventional columns numerical calculations. latter conducted non-isothermal, two-dimensional model that not only considers increase porosity velocity wall, but also expresses effective transport coefficients as functions radial coordinate. provides reasonable accuracy under for which usual plug-flow assumption questionable.

参考文章(36)
Ahmet R Özdural, Aslı Alkan, Piet J.A.M Kerkhof, Modeling chromatographic columns. Non-equilibrium packed-bed adsorption with non-linear adsorption isotherms Journal of Chromatography A. ,vol. 1041, pp. 77- 85 ,(2004) , 10.1016/J.CHROMA.2004.05.009
A.S. Moharir, D. Kunzru, D.N. Saraf, Modelling of nonisothermal packed bed sorption on uniform and nonuniform zeolite crystals Zeolites. ,vol. 2, pp. 155- 161 ,(1982) , 10.1016/S0144-2449(82)80045-6
C.B Ching, Y.X Wu, M Lisso, G Wozny, T Laiblin, W Arlt, Study of feed temperature control of chromatography using computional fluid dynamics simulation Journal of Chromatography A. ,vol. 945, pp. 117- 131 ,(2002) , 10.1016/S0021-9673(01)01479-0
C. O. Castillo-Araiza, H. Jiménez-Islas, F. López-Isunza, Heat-transfer studies in packed-bed catalytic reactors of low tube/particle diameter ratio Industrial & Engineering Chemistry Research. ,vol. 46, pp. 7426- 7435 ,(2007) , 10.1021/IE070097Z
H.J. Bart, R. Germerdonk, P. Ning, Two-dimensional non-isothermal model for toluene adsorption in a fixed-bed adsorber Chemical Engineering and Processing. ,vol. 35, pp. 57- 64 ,(1996) , 10.1016/0255-2701(95)04114-1
Witold Kwapinski, Combined wall and thermal effects during non-isothermal packed bed adsorption Chemical Engineering Journal. ,vol. 152, pp. 271- 276 ,(2009) , 10.1016/J.CEJ.2009.05.023
L. Marletta, G. Maggio, A. Freni, M. Ingrasciotta, G. Restuccia, A non-uniform temperature non-uniform pressure dynamic model of heat and mass transfer in compact adsorbent beds International Journal of Heat and Mass Transfer. ,vol. 45, pp. 3321- 3330 ,(2002) , 10.1016/S0017-9310(02)00045-5
B PAN, F MENG, X CHEN, B PAN, X LI, W ZHANG, X ZHANG, J CHEN, Q ZHANG, Y SUN, Application of an effective method in predicting breakthrough curves of fixed-bed adsorption onto resin adsorbent Journal of Hazardous Materials. ,vol. 124, pp. 74- 80 ,(2005) , 10.1016/J.JHAZMAT.2005.03.052