Synthesis and characterization of a recoverable rhodium catalyst with a stimulus sensitive polymer ligand
作者： Wendy J. Shaw , John C. Linehan , Anna Gutowska , David Newell , Tom Bitterwolf
DOI: 10.1016/J.INOCHE.2005.07.001
关键词:
摘要: Abstract We report the synthesis and characterization of a rhodium catalyst attached to polymer which is designed control reactivity in response an applied stimulus. The precursor, Rh(Cl)(CO) 2 (NH -polymer), was prepared from poly N -isopropylacrylamide (pNIPAAm) [Rh(Cl)(CO) ] . structure metal complex interrogated using IR, Raman, UV/Vis, NMR XAFS, catalytic activity tested aqueous hydrogenation reaction.
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