A combined experimental and theoretical study on an ionic cobalt(III/II) complex with a Schiff base ligand
作者： Kousik Ghosh , Tamal Dutta , Michael G.B. Drew , Antonio Frontera , Shouvik Chattopadhyay
DOI: 10.1016/J.POLY.2020.114432
关键词:
摘要: Abstract An ionic cobalt(III/II) complex, [CoIII(L)2][CoII(NCS)3(H2O)], where H2L = 2-((3-aminopropylimino)methyl)-6-methoxyphenol, has been synthesized and characterized by several analytical techniques, including single crystal X-ray diffraction analysis. The energetic features of the solid state non-covalent interactions involved in titled coordination complex have studied means DFT computations, which indicate that a combination strong CH3···π H-bonding is main reason behind stabilization this complex.
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