Homogeneous metallocene ziegler-natta catalysts for the oligomerization of olefins in aliphatic-hydrocarbon solvents

作者: Michael E. Wright

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摘要: An approach that permits continuous batch conversion of alpha-olefins and internal-olefins to oligomeric materials without fouling the reaction vessel provides a simple highly efficient method for making very cost effective catalyst systems based on Zeigler-Natta Group 4 metallocenes. Embodiments this invention produce diesel turbine fuels are 100% synthetic iso-paraffinic kerosenes with flashpoints greater than 61 deg C.

参考文章(59)
Kevin S. Ratliff, Vahid Bagheri, David C. Eisenberg, Carroll W. Lanier, Ranier Benda, Oligomer oils and their manufacture ,(2000)
John F. Walzer, Catalina L. Coker, Peijun Jiang, Margaret May-Som Wu, Process to produce low viscosity poly-alpha-olefins ,(2006)
Frederick A. Myers, Leroy R. Price, Antimicrobial coated metal sheet ,(2001)
Roxanne L. Quintana, Michael E. Wright, Benjamin G. Harvey, Diesel and jet fuels based on the oligomerization of butene ,(2009)
Stacy M. Burns-Guydish, Gregory W. Luli, Robert Eckert, David C. Walther, Eamon T. Hogg, Richard W. Wilson, Hendrik J. Meerman, Integrated system and process for bioproduct production ,(2010)
Volker Dolle, Frank Kuber, Jurgen Rohrmann, Andreas Winter, Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands ,(1995)
Shakeel Tirmizi, Norman Yang, Mark Paul Hagemeister, Margaret May-Som Wu, Process to produce polyolefins using metallocene catalysts ,(2007)
Cesar Alberto Garcia-Franco, David Raymond Johnsrud, Ramin Abhari, Armenag Hagop Dekmezian, Charles Lewis Sims, Jo Ann Marie Canich, Peijun Jiang, Multiple catalyst system for olefin polymerization and polymers produced therefrom ,(2003)