Studies on semi-organic (C8H11NO)2[ZnCl4] single crystal for nonlinear optical (NLO) applications
作者： P. Karuppasamy , D. Joseph Daniel , H.J. Kim , M. Senthil Pandian , P. Ramasamy
DOI: 10.1016/J.JCRYSGRO.2020.125528
关键词:
摘要: Abstract Optically high quality metal-organic nonlinear optical (NLO) single crystals of bis(4-methoxybenzylammonium) tetrachloridozincate (4MBZ) have been harvested from the aqueous solution by growth technique. The crystal X-ray diffraction (SXRD) results shows grown 4MBZ forms monoclinic system with space group P21. Powder (PXRD) pattern has recorded in 2θ range 10–60° to confirm various types crystalline planes and phase purity. Hirshfield surface on carried out finding intermolecular interactions. From Fourier transform infrared (FTIR) spectroscopy analysis, functional groups were confirmed. transparency band gap energy studied UV–Vis NIR spectral studies. Resultant, good entire visible near IR region. sample was subjected Thermogravimetric analysis (TGA) differential Scanning colorimetry (DSC) study thermal behaviour. chemical etching analyses dislocation density. parameters such as refractive index (n2), absorption coefficient (β) third order susceptibility (χ(3)) analyzed Z-scan method using diode laser 532 nm.
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sci-hub.st 参考文章(21)
John Coates, Interpretation of Infrared Spectra, A Practical Approach Encyclopedia of Analytical Chemistry. ,(2006) , 10.1002/9780470027318.A5606
Zhi-Gang Zang, Yu-Jun Zhang, Low-switching power (<45 mW) optical bistability based on optical nonlinearity of ytterbium-doped fiber with a fiber Bragg grating pair Journal of Modern Optics. ,vol. 59, pp. 161- 165 ,(2012) , 10.1080/09500340.2011.622842
Mark A. Spackman, Dylan Jayatilaka, Hirshfeld surface analysis CrystEngComm. ,vol. 11, pp. 19- 32 ,(2009) , 10.1039/B818330A
Chenlin Du, Bing Teng, Zhengping Wang, Junhai Liu, Xinguang Xu, Guibao Xu, Kun Fu, Jiyang Wang, Yaogang Liu, Zongshu Shao, Actively Q-switched intracavity second-harmonic generation of in BiB3O6 crystal Optics & Laser Technology. ,vol. 34, pp. 343- 346 ,(2002) , 10.1016/S0030-3992(02)00027-0
Zhigang Zang, All-optical switching in Sagnac loop mirror containing an ytterbium-doped fiber and fiber Bragg grating Applied Optics. ,vol. 52, pp. 5701- 5706 ,(2013) , 10.1364/AO.52.005701
J. Tauc, A. Menth, States in the gap Journal of Non-crystalline Solids. pp. 569- 585 ,(1972) , 10.1016/0022-3093(72)90194-9
Zhigang Zang, Numerical analysis of optical bistability based on Fiber Bragg Grating cavity containing a high nonlinearity doped-fiber Optics Communications. ,vol. 285, pp. 521- 526 ,(2012) , 10.1016/J.OPTCOM.2011.11.023
D. Joseph Daniel, P. Ramasamy, Studies on the nonlinear optical single crystal: Ammonium d,l-tartrate (C4H9NO6) Materials Research Bulletin. ,vol. 47, pp. 708- 713 ,(2012) , 10.1016/J.MATERRESBULL.2011.12.009
Zhigang Zang, Yujun Zhang, Analysis of optical switching in a Yb 3+ -doped fiber Bragg grating by using self-phase modulation and cross-phase modulation Applied Optics. ,vol. 51, pp. 3424- 3430 ,(2012) , 10.1364/AO.51.003424
M. Sheik-Bahae, A.A. Said, T.-H. Wei, D.J. Hagan, E.W. Van Stryland, Sensitive measurement of optical nonlinearities using a single beam IEEE Journal of Quantum Electronics. ,vol. 26, pp. 760- 769 ,(1990) , 10.1109/3.53394