Effect of Temperature on the Shear-Thickening Behavior of Fumed Silica Suspensions.

作者: Justin Warren , Sean Offenberger , Hossein Toghiani , Charles U. Pittman , Thomas E. Lacy

DOI: 10.1021/ACSAMI.5B05094

关键词:

摘要: Shear-thickening fluids (STFs) can be subjected to a significant temperature variation in many applications. Polymeric or oligomeric are commonly used as suspending media for STFs. Because the viscosities of polymeric strongly temperature-dependent, large changes profoundly affect shear-thickening responses. Here, effect on behavior four low-molecular-weight glycols/fumed silica suspensions is reported. The dispersed-phase volume fraction, its surface chemistry, and chemical compositions were varied. These factors influence viscosity interactions between suspended particles media. Fumed with two different silanol-group densities glycols, where these silanol groups formed hydrogen bonds media’s glycols internal oxygen atoms. Steady-shear experiments performed ove...

参考文章(38)
Young S. Lee, E. D. Wetzel, N. J. Wagner, The ballistic impact characteristics of Kevlar® woven fabrics impregnated with a colloidal shear thickening fluid Journal of Materials Science. ,vol. 38, pp. 2825- 2833 ,(2003) , 10.1023/A:1024424200221
H. Barthel, L. Rsch, J. Weis, Fumed Silica ‐ Production, Properties, and Applications Organosilicon Chemistry Set: From Molecules to Materials. pp. 761- 778 ,(2008) , 10.1002/9783527620777.CH91A
Johann Mathias, Gerhard Wannemacher, Basic characteristics and applications of aerosil Journal of Colloid and Interface Science. ,vol. 125, pp. 61- 68 ,(1988) , 10.1016/0021-9797(88)90054-9
Vincent T. O'Brie, Michael E. Mackay, Stress Components and Shear Thickening of Concentrated Hard Sphere Suspensions Langmuir. ,vol. 16, pp. 7931- 7938 ,(2000) , 10.1021/LA000050H
Romain Mari, Ryohei Seto, Jeffrey F. Morris, Morton M. Denn, Shear thickening, frictionless and frictional rheologies in non-Brownian suspensions Journal of Rheology. ,vol. 58, pp. 1693- 1724 ,(2014) , 10.1122/1.4890747
Brian Vincent, John Edwards, Simon Emmett, Andrew Jones, None, Depletion flocculation in dispersions of sterically-stabilised particles (“soft spheres”) Colloids and Surfaces. ,vol. 18, pp. 261- 281 ,(1986) , 10.1016/0166-6622(86)80317-1
M. Wyart, M. E. Cates, Discontinuous Shear Thickening without Inertia in Dense Non-Brownian Suspensions Physical Review Letters. ,vol. 112, pp. 098302- ,(2014) , 10.1103/PHYSREVLETT.112.098302
Thomas Glomann, Adrian Hamm, Jürgen Allgaier, Eike G. Hübner, Aurel Radulescu, Bela Farago, Gerald J. Schneider, A microscopic view on the large scale chain dynamics in nanocomposites with attractive interactions Soft Matter. ,vol. 9, pp. 10559- 10571 ,(2013) , 10.1039/C3SM51194D
Nicolas Fernandez, Roman Mani, David Rinaldi, Dirk Kadau, Martin Mosquet, Hélène Lombois-Burger, Juliette Cayer-Barrioz, Hans J. Herrmann, Nicholas D. Spencer, Lucio Isa, Microscopic mechanism for shear thickening of non-Brownian suspensions. Physical Review Letters. ,vol. 111, pp. 108301- ,(2013) , 10.1103/PHYSREVLETT.111.108301
Jan Mewis, Gary Biebaut, Shear thickening in steady and superposition flows effect of particle interaction forces Journal of Rheology. ,vol. 45, pp. 799- 813 ,(2001) , 10.1122/1.1359761