Mild uncatalyzed hydroamination of an electrophilic alkyne, ethynylcobalticinium

作者: Yanlan Wang , Amalia Rapakousiou , Camille Latouche , Jean-Claude Daran , Anu Singh

DOI: 10.1039/C3CC42211A

关键词:

摘要: Primary and secondary amines react with ethynylcobalticinium under mild conditions in the absence of a catalyst an additional solvent to give quantitative yields dark-red microcrystalline cobalticinium trans-enamines that show remarkable push–pull electronic structure.

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