Crosslinking photocopolymerization of acrylic acid (and N‐vinylpyrrolidone) with triethyleneglycol dimethacrylate initiated by camphorquinone/ethyl‐4‐dimethylaminobenzoate

作者: J. Jakubiak , J. Nie , L.-�. Lind�n , J. F. Rabek

DOI: 10.1002/(SICI)1099-0518(20000301)38:5<876::AID-POLA12>3.0.CO;2-N

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摘要: In this article, we report the camphorquinone/amine visible-light-induced photocopolymerization of monofunctional acrylic acid (AA), N-vinylpyrrolidone (NVP), or both with difunctional triethyleneglycol dimethacrylate (TEGDMA) monomers followed by crosslinking pendant double-bond groups resulting homopolymers and copolymers. Our primary objective was to study photocopolymerizability various mixtures AA, NVP, TEGDMA compositions at different molar ratios in air. The AA occurred formation two peaks rates polymerization. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Chem 38: 876–886,

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