Analyse conformationnelle theorique (methode CNDO/2) de quelques composes ditertiobutyles du phosphore (III) P(t-Bu)2X (X = H,F)
作者： Monique Corosine , François Crasnier
DOI: 10.1016/0022-2860(75)85127-1
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摘要: Abstract Optimized geometries and conformational analysis of P(t-Bu) 2 F H molecules are investigated within the framework CNDO/2 approximation. The CPC angles found to be equal 114° in agreement with 113°8 value provided by X-ray study trans-NiBr [P(t-Bu) F] square planar complex. Therefore, it seems that highest XPX PX 3 series is observed for di-tert-butyl derivatives not tri-tert-butylphosphine.
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