Effects of temperature on nitration of sulfamates
作者： Yuji Sugie , Atsumi Miyake
DOI: 10.1007/S10973-014-3688-4
关键词:
摘要: Ammonium dinitramide (ADN) has attracted great interest as a potential oxidizer for next generation rocket propellants. It is halogen-free alternative to ammonium perchlorate, which currently in wide used solid propellant oxidizer. However, ADN synthesis, N-nitration necessary form the N-(NO2)2 group. Using reaction calorimeter, thermal behavior of nitration sulfamates (K, Na, and NH4) using mixture acids (HNO3/H2SO4 HNO3/AcOH) agent was examined. The heat decomposition potassium sulfamate at −10 °C greater than that 20 °C. decreased following order: K salt>Na salt>NH4 salt HNO3/H2SO4. dipole moments were calculated, results revealed electronic states nitrogen different. Thus, affect sulfamates. HNO3/AcOH larger
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sci-hub.se 参考文章(16)
Kazuo Shiino, Toshio Onda, Shigefumi Miyazaki, Hideo Hatano, Shigeru Suzuki, Synthetic method for forming ammonium dinitrammide (ADN) ,(1996)
Robert J. Schmitt, Paul E. Penwell, David C. Bomberger, Jeffrey C. Bottaro, Process for forming ammonium dinitramide salt by reaction between ammonia and a nitronium-containing compound ,(1991)
Henric Östmark, Abraham Langlet, Niklas Wingborg, Method of preparing dinitramidic acid and salts thereof ,(1996)
John H. Ridd, Mechanism of aromatic nitration Accounts of Chemical Research. ,vol. 4, pp. 248- 253 ,(1971) , 10.1021/AR50043A003
H. Östmark, U. Bemm, A. Langlet, R. Sandén, N. Wingborg, The properties of ammonium dinitramide (ADN): Part 1, basic properties and spectroscopic data Journal of Energetic Materials. ,vol. 18, pp. 123- 138 ,(2000) , 10.1080/07370650008216116
Hiroki Matsunaga, Hiroto Habu, Atsumi Miyake, Influences of aging on thermal decomposition mechanism of high performance oxidizer ammonium dinitramide Journal of Thermal Analysis and Calorimetry. ,vol. 113, pp. 1387- 1394 ,(2013) , 10.1007/S10973-013-3186-0
Martin Cupery, SULFAMIC ACID A NEW INDUSTRIAL CHEMICAL Industrial & Engineering Chemistry. ,vol. 30, pp. 627- 631 ,(1938) , 10.1021/IE50342A005
Gerard S. Harbison, Young-Sik Kye, Glenn H. Penner, Michelle Grandin, Martine Monette, 14N Quadrupolar,14N and15N Chemical Shift, and14N−1H Dipolar Tensors of Sulfamic Acid The Journal of Physical Chemistry B. ,vol. 106, pp. 10285- 10291 ,(2002) , 10.1021/JP0261962
V. Yang, R. Yang, P. Thakre, Thermal Decomposition and Combustion of Ammonium Dinitramide (Review) Combustion, Explosion, and Shock Waves. ,vol. 41, pp. 657- 679 ,(2005) , 10.1007/S10573-005-0079-Y
A. N. Pavlov, V. N. Grebennikov, L. D. Nazina, G. M. Nazin, G. B. Manelis, Thermal decomposition of ammonium dinitramide and mechanism of anomalous decay of dinitramide salts Russian Chemical Bulletin. ,vol. 48, pp. 50- 54 ,(1999) , 10.1007/BF02494399