Formation of P-C bonds under unexpectedly mild conditions. Phosphoryl migration and metal coordination of diphenylphosphinomethyl-oxazolines and -thiazolines.
作者： Roberto Pattacini , Günter Margraf , Abdelatif Messaoudi , Nicola Oberbeckmann-Winter , Pierre Braunstein
DOI: 10.1021/IC800934H
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摘要: The heterocycles 2-methyl-2-oxazoline (mox) and 2-methyl-2-thiazoline (mth) react with Ph2PCl under mild conditions, in the presence of NEt3 which promotes their phosphorylation by stabilization of...
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