Alkane Oxidation: Estimation of Alkyl Hydroperoxide Content by Gc Analysis of the Reaction Solution Samples Before and after Reduction with Triphenylphosphine

摘要: This publication describes a very simple method which we developed in our earlier works devoted to the alkane oxidations with hydrogen peroxide as well by air under visible light irradiation. is based on comparison of chromatograms reaction solution made before and after treatment sample triphenylphosphine (if PPh insoluble mixture, for example, water solution, other reducing agents, such NaBH or NaSO can be used). One merits this possibility estimate concentration alkyl hydroperoxide formed from presence an excess oxidant (hydrogen peroxide, metal peroxide).