C−C, C−S, and C−N Coupling versus Dealkylation Processes in the Cationic Tris(thiolato)dimolybdenum(III) Complexes [Mo2Cp2(μ-SMe)3L2]+ (L = xylNC, t-BuNC, CO, MeCN)
作者： Wilfried-Solo Ojo , François Y Pétillon , P Schollhammer , Jean Talarmin , None
DOI: 10.1021/OM8003702
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摘要: Reductive coupling between isocyanide ligands attached to adjacent molybdenum atoms in the bis(aryl isocyanide) complex [Mo2Cp2(μ-SMe)3(xylNC)2](BF4) (1) was initiated by addition of hydrosulfi...
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sci-hub.se 参考文章(108)
J. Birnbaum, M. Rakowski DuBois, Reactions of a Cationic Molybdenum Complex with Olefins. 2. Oligomerization of Terminal Branched Olefins Organometallics. ,vol. 13, pp. 1014- 1019 ,(1994) , 10.1021/OM00015A039
Paul M. Treichel, Transition Metal-lsocyanide Complexes Advances in Organometallic Chemistry. ,vol. 11, pp. 21- 86 ,(1973) , 10.1016/S0065-3055(08)60159-8
Jan H. Teuben, Rosa. Fandos, Auke. Meetsma, Formation of η1-Iminoacyl Compounds by Insertion of Isonitriles in Pentamethylcyclopentadienyl-Tetramethylfulvene Compounds of Titanium and Zirconium. Intramolecular C-H Activation of a Pentamethylcyclopentadienyl Group To Give a Tridentate Ligand with T Organometallics. ,vol. 10, ,(1991) , 10.1021/OM00054A030
Simon F. T. Froom, Michael Green, Richard J. Mercer, Katherine R. Nagle, A. Guy Orpen, Richard A. Rodrigues, Reactions of co-ordinated ligands. Part 53. Synthesis of dimolybdenum and ditungsten µ-σ,η2-(4e)-vinylidene and -allenylidene complexes; crystal structures of [N(PPh3)2][Mo2{µ-σ:η2-(3e)-C2Ph}(CO)4(η5-C9H7)2], [Mo2{µ-σ:η2-(4e)-CC(Ph)(CH2)4OMe}(CO)4(η-C5H5)2] and [Mo2{µ-σ:η2-(4e)-CCCMe2}(CO)4(η-C5H5)2] Journal of The Chemical Society-dalton Transactions. pp. 3171- 3183 ,(1991) , 10.1039/DT9910003171
Gregory J. Kubas, Robert R. Ryan, Kimberly A. Kubat-Martin, Cleavage of sulfur dioxide on (.eta.5-C5Me5)2Mo2(.mu.-S2)(.mu.-S)2 to form S8 and a thiosulfate complex (.eta.5-C5Me5)2Mo2(.mu.-S2)(.mu.-S)(.mu.-SSO3). Possible role in homogeneous hydrogenation of sulfur dioxide catalyzed by molybdenum-sulfur complexes Journal of the American Chemical Society. ,vol. 111, pp. 7823- 7832 ,(1989) , 10.1021/JA00202A024
Yoshitha A. Wanniarachchi, LeGrande M. Slaughter, One-step assembly of a chiral palladium bis(acyclic diaminocarbene) complex and its unexpected oxidation to a bis(amidine) complex Chemical Communications. pp. 3294- 3296 ,(2007) , 10.1039/B703769D
Philippe Schollhammer, Erwann Guénin, François Y. Pétillon, Jean Talarmin, Kenneth W. Muir, Dmitri S. Yufit, η1−η2 Rearrangement and Protonation of Phenyldiazo Bridging Ligands Attached to the Dimolybdenum System {Mo2Cp2(μ-SMe)3} Organometallics. ,vol. 17, pp. 1922- 1924 ,(1998) , 10.1021/OM971114V
P. Schollhammer, F.Y. Pétillon, J. Talarmin, Kenneth W. Muir, The effect of replacing carbonyl with acetonitrile on the reactivity of the bimetallic system [Mo2Cp2(μ-SMe)3(L)2]+ (L=CO, CH3CN). Crystal structure of [Mo2Cp2(μ-SMe)2(CH3CN)4](BF4)2 Inorganica Chimica Acta. ,vol. 284, pp. 107- 111 ,(1999) , 10.1016/S0020-1693(98)00266-7
Linda L. Lopez, P. Bernatis, J. Birnbaum, R. C. Haltiwanger, M. Rakowski DuBois, Mechanistic study of hydrogen activation by cationic dinuclear (.mu.-sulfido)molybdenum complexes Organometallics. ,vol. 11, pp. 2424- 2435 ,(1992) , 10.1021/OM00043A025
Rachel Newell, Claire Ohman, M. Rakowski DuBois, Reactions of Sulfido-Bridged Molybdenum Dimers with Diynes as a Route to Multinuclear Dithiolene Complexes Organometallics. ,vol. 24, pp. 4406- 4415 ,(2005) , 10.1021/OM050317D