Design and synthesis of an exceptionally stable and highly porous metal-organic framework
作者： Hailian Li , Mohamed Eddaoudi , M. O'Keeffe , O. M. Yaghi
DOI: 10.1038/46248
关键词:
摘要: Open metal–organic frameworks are widely regarded as promising materials for applications,,,,,,,,,,,,,, in catalysis, separation, gas storage and molecular recognition. Compared to conventionally used microporous inorganic materials such as zeolites, these organic structures have the potential for more flexible rational design, through control of the architecture and functionalization of the pores. So far, the inability of these open frameworks to support permanent porosity and to avoid collapsing in the absence of guest molecules …
nature.com
harvard.edu
scilit.net参考文章(20)
Donald W Breck, Zeolite molecular sieves Krieger. ,(1984)
Feng-Quan Liu, Feng-Quan Liu, T. Don Tilley, A coordination network based on d0 transition-metal centers: synthesis and structure of the [2,4]-connected layered compound [(TiCl4)2Si(C6H4CN-p)4]·1.5C7H8 Chemical Communications. pp. 103- 104 ,(1998) , 10.1039/A706020C
Yukio Kinoshita, Ikuo Matsubara, Taiichi Higuchi, Yoshihiko Saito, The Crystal Structure of Bis(adiponitrilo)copper(I) Nitrate Bulletin of the Chemical Society of Japan. ,vol. 32, pp. 1221- 1226 ,(1959) , 10.1246/BCSJ.32.1221
Bernard F. Hoskins, Richard Robson, Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments Journal of the American Chemical Society. ,vol. 111, pp. 5962- 5964 ,(1989) , 10.1021/JA00197A079
O. M. Yaghi, Guangming Li, Hailian Li, Selective binding and removal of guests in a microporous metal–organic framework Nature. ,vol. 378, pp. 703- 706 ,(1995) , 10.1038/378703A0
Leonard R. MacGillivray, Ryan H. Groeneman, Jerry L. Atwood, DESIGN AND SELF-ASSEMBLY OF CAVITY-CONTAINING RECTANGULAR GRIDS Journal of the American Chemical Society. ,vol. 120, pp. 2676- 2677 ,(1998) , 10.1021/JA973584M
Susumu Kitagawa, Megumu Munakata, Tadashi Tanimura, Tetranuclear Copper(I)-Based Infinite One-Dimentional Chain Complex. Synthesis and X-Ray Crystal Structure of {[Cu2(μ-3-methylpyridazine)2(μ-pyrazine)3](ClO4)2}∞ Chemistry Letters. ,vol. 20, pp. 623- 626 ,(1991) , 10.1246/CL.1991.623
Thomas P. Vaid, Emil B. Lobkovsky, Peter T. Wolczanski, Covalent 3- and 2-Dimensional Titanium−Quinone Networks Journal of the American Chemical Society. ,vol. 119, pp. 8742- 8743 ,(1997) , 10.1021/JA971658O
Jian Lu, Tasneem Paliwala, Shiao C. Lim, Carolyn Yu, Tianyan Niu, Allan J. Jacobson, Coordination Polymers of Co(NCS)2 with Pyrazine and 4,4‘-Bipyridine: Syntheses and Structures Inorganic Chemistry. ,vol. 36, pp. 923- 929 ,(1997) , 10.1021/IC961158G
Geoffrey B. Gardner, D. Venkataraman, Jeffrey S. Moore, Stephen Lee, Spontaneous assembly of a hinged coordination network Nature. ,vol. 374, pp. 792- 795 ,(1995) , 10.1038/374792A0