Spectroscopic investigation of tetrahydroisoquinoline in supersonic jet

作者: Abhijit Chakraborty , Nikhil Guchhait , Sudip Banerjee , Debnarayan Nath , G. Naresh Patwari

DOI: 10.1063/1.1394742

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摘要: Fluorescence excitation and dispersed emission spectra of tetrahydroisoquinoline are presented here. Two bands at 36 781 36 884 cm−1 confirmed from the spectral hole burning studies as two origins for conformers. These correspond to inequivalent twist conformers with hydrogen atom attached nitrogen axial equatorial positions, respectively. The former is found be most stable one. SVL explained on basis theoretically calculated low-frequency vibrations. butterfly puckering motions benzene chromophore,

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