作者: Kilian Muñiz , Belén García , Claudio Martínez , Alessandro Piccinelli , None
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摘要: The general synthesis, isolation and characterization of electrophilic iodine reagents the formula R4 N[I(O2 CAr)2 ] is reported. These compounds are air- moisture-stable iodine(I) reagents, which were characterized including X-ray analysis. They represent conceptually new with anions as stabilizers. display expected performance upon interaction electron-rich substrates. these in a total 47 different reactions vicinal iodooxygenation alkenes studied some key features on revealed.