Dioxoiodane Compounds as Versatile Sources for Iodine(I) Chemistry

作者: Kilian Muñiz , Belén García , Claudio Martínez , Alessandro Piccinelli , None

DOI: 10.1002/CHEM.201603801

关键词:

摘要: The general synthesis, isolation and characterization of electrophilic iodine reagents the formula R4 N[I(O2 CAr)2 ] is reported. These compounds are air- moisture-stable iodine(I) reagents, which were characterized including X-ray analysis. They represent conceptually new with anions as stabilizers. display expected performance upon interaction electron-rich substrates. these in a total 47 different reactions vicinal iodooxygenation alkenes studied some key features on revealed.

参考文章(66)
Mekhman S. Yusubov, Viktor V. Zhdankin, Iodine catalysis: A green alternative to transition metals in organic chemistry and technology Resource-Efficient Technologies. ,vol. 1, pp. 49- 67 ,(2015) , 10.1016/J.REFFIT.2015.06.001
Claudio Martínez, Kilian Muniz, None, An Iodine-Catalyzed Hofmann–Löffler Reaction† Angewandte Chemie. ,vol. 54, pp. 8287- 8291 ,(2015) , 10.1002/ANIE.201501122
Ralf W. Troff, Toni Mäkelä, Filip Topić, Arto Valkonen, Kari Raatikainen, Kari Rissanen, Alternative Motifs for Halogen Bonding European Journal of Organic Chemistry. ,vol. 2013, pp. 1617- 1637 ,(2013) , 10.1002/EJOC.201201512
Carmen Álvarez-Rúa, Santiago García-Granda, Alfredo Ballesteros, Francisco González-Bobes, José M. González, Bis­(pyridine)­iodo­nium(I) tetra­fluoro­borate Acta Crystallographica Section E-structure Reports Online. ,vol. 58, ,(2002) , 10.1107/S1600536802020639
Mohammad Alikarami, Mansoureh Farhadi, Benzyl(triphenyl)phosphonium Dichloroiodate: A New Reagent for Coiodination of Alkenes Helvetica Chimica Acta. ,vol. 98, pp. 1302- 1306 ,(2015) , 10.1002/HLCA.201500069
José Barluenga, José M. González, Pedro J. Campos, Gregorio Asensio, I(py)2BF4, ein neues Reagens: allgemeine Methode für die 1,2‐Iodfunktionalisierung von Olefinen Angewandte Chemie. ,vol. 97, pp. 341- 342 ,(1985) , 10.1002/ANGE.19850970430
Rosendo Hernández, Augusto Rivera, José A. Salazar, Ernesto Suárez, Nitroamine radicals as intermediates in the functionalization of non-activated carbon atoms Journal of The Chemical Society, Chemical Communications. pp. 958- 959 ,(1980) , 10.1039/C39800000958
Anton Lishchynskyi, Kilian Muñiz, An Approach to the Regioselective Diamination of Conjugated Di‐ and Trienes Chemistry: A European Journal. ,vol. 18, pp. 2212- 2216 ,(2012) , 10.1002/CHEM.201103435
Renhua Fan, Dongming Pu, Fengqi Wen, Jie Wu, δ and α SP3 C-H bond oxidation of sulfonamides with Phi(OAc)2/I2 under metal-free conditions Journal of Organic Chemistry. ,vol. 72, pp. 8994- 8997 ,(2007) , 10.1021/JO7016982
Pedro de Armas, Cosme G. Francisco, Rosendo Hernández, José A. Salazar, Ernesto Suárez, Steroidal N-nitroamines. Part 4. Intramolecular functionalization of N-nitroamine radicals: synthesis of 1,4-nitroimine compounds Journal of The Chemical Society-perkin Transactions 1. pp. 3255- 3265 ,(1988) , 10.1039/P19880003255