Synthesis of Phosphirane Oxide Derivatives Promoted by Introduced Phenylsulfinyl Groups and Their Pummerer Reaction
作者： Tatsuo Oshikawa , Mitsuji Yamashita
DOI: 10.1246/BCSJ.59.3293
关键词:
摘要: Phosphirane oxide derivatives were first successfully synthesized in good yield under mild conditions wherein carbon–carbon bond formation was promoted by two phenylsulfinyl groups on the α and α′ carbons of phosphorus atom. A structure determination formed phosphirane as well stereochemistry Pummerer reaction product revealed a trans geometry for oxide.
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