Strontium adsorption and desorption in wetlands: Role of organic matter functional groups and environmental implications.

作者: Antoine Boyer , Paris Ning , Doug Killey , Martin Klukas , David Rowan

DOI: 10.1016/J.WATRES.2018.01.026

关键词:

摘要: Strontium (Sr) is a chemical element that often used as tracer in hydrogeochemical studies, and ubiquitously distributed radioactive contaminant nuclear sites the form of strontium-90 (Sr-90). At interface between groundwater surface water, wetlands possess unique properties whose impact on Sr transport has not been investigated thoroughly. In this study, adsorption desorption was six natural wetland substrates two mixes exogenous media sediment: winter summer sediments, decayed cattails, wood, leaf litter, moss, bone charcoal, clinoptilolite. The composition organic matter characterized using carbon-13, solid phase Nuclear Magnetic Resonance analysis. range substrates' coefficients obtained could be explained by factors indicative proteins matter, which were shown to support strong poorly reversible adsorption. contrast, proportion carbohydrates lignin found lower higher desorption. implications these results for pollution remediation are discussed.

参考文章(54)
L Dewiere, D Bugai, C Grenier, V Kashparov, N Ahamdach, None, 90Sr migration to the geo-sphere from a waste burial in the Chernobyl exclusion zone. Journal of Environmental Radioactivity. ,vol. 74, pp. 139- 150 ,(2004) , 10.1016/J.JENVRAD.2004.01.019
M. V. Fedorkova, E. P. Pakhnenko, N. I. Sanzharova, Chemical forms of radioactive strontium interaction with organic matter of different soil types Moscow University Soil Science Bulletin. ,vol. 67, pp. 133- 136 ,(2012) , 10.3103/S0147687412030027
Ralf Dahlqvist, Marc F. Benedetti, Karen Andersson, David Turner, Tobias Larsson, Björn Stolpe, Johan Ingri, Association of calcium with colloidal particles and speciation of calcium in the Kalix and Amazon rivers Geochimica et Cosmochimica Acta. ,vol. 68, pp. 4059- 4075 ,(2004) , 10.1016/J.GCA.2004.04.007
Vasileios Mavromatis, Jérôme Chmeleff, Pierre Brunet, Yuriy V. Alekhin, Hélène Isnard, Oleg S. Pokrovsky, Svetlana M. Ilina, Jérôme Viers, Sergey A. Lapitsky, Sebastian Mialle, Stable (Cu, Mg) and radiogenic (Sr, Nd) isotope fractionation in colloids of boreal organic-rich waters Chemical Geology. ,vol. 342, pp. 63- 75 ,(2013) , 10.1016/J.CHEMGEO.2013.01.019
Daniel I. Kaplan, Saijin Zhang, Kimberly A. Roberts, Kathy Schwehr, Chen Xu, Danielle Creeley, Yi-Fang Ho, Hsiu-Ping Li, Chris M. Yeager, Peter H. Santschi, Radioiodine concentrated in a wetland. Journal of Environmental Radioactivity. ,vol. 131, pp. 57- 61 ,(2014) , 10.1016/J.JENVRAD.2013.09.001
I Smičiklas, S Dimović, M Jović, A Milenković, M Šljivić-Ivanović, None, Evaluation study of cobalt(II) and strontium(II) sorption–desorption behavior for selection of soil remediation technology International Journal of Environmental Science and Technology. ,vol. 12, pp. 3853- 3862 ,(2015) , 10.1007/S13762-015-0817-Y
Jyh-Ping Chen, Batch and continuous adsorption of strontium by plant root tissues Bioresource Technology. ,vol. 60, pp. 185- 189 ,(1997) , 10.1016/S0960-8524(97)00021-7
Yan Gao, Amy T. Kan, Mason B. Tomson, Critical evaluation of desorption phenomena of heavy metals from natural sediments. Environmental Science & Technology. ,vol. 37, pp. 5566- 5573 ,(2003) , 10.1021/ES034392W
I. Smičiklas, S. Dimović, I. Plećaš, Removal of Cs1+, Sr2+ and Co2+ from aqueous solutions by adsorption on natural clinoptilolite Applied Clay Science. ,vol. 35, pp. 139- 144 ,(2007) , 10.1016/J.CLAY.2006.08.004