Microstructure and electrical properties of iron oxide thin films deposited by spray pyrolysis

作者: Alaa A Akl

DOI: 10.1016/S0169-4332(03)00951-6

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摘要: Abstract Microstructure and electrical properties of iron oxide Fe 2 O 3 thin films prepared by spray pyrolysis method have been experimentally characterized. The effect substrate temperature as well deposition time on the structural features (crystallite size microstrain) electric resistivity these has investigated. X-ray diffraction (XRD) scanning electron microscope (SEM) characterized structure study. results showed that with increasing bias film changed from amorphous to crystalline at same time. At a 350 °C low time, α-Fe appears almost in form. With rising crystallinity was improved. T sub >350 °C, well-crystallized rhombohedral phase obtained. Single order Voigt profile used determine microstructure parameters. measured value crystallite microstrain different temperatures times were studied. dark measurements room values 2.122×10 5  Ω cm for three orders magnitude lower than films.

参考文章(20)
R. F. Penoyer, L. R. Bickford, Magnetic Annealing Effect in Cobalt-Substituted Magnetite Single Crystals Physical Review. ,vol. 108, pp. 271- 277 ,(1957) , 10.1103/PHYSREV.108.271
A. K. Abass, H. A. Jassim, K. J. Majeid, R. H. Misho, Optical Parameters of Chemically Deposited Tin Disulphide physica status solidi (a). ,vol. 91, pp. 129- 133 ,(1985) , 10.1002/PSSA.2210910117
M. Matsumoto, A. Morisako, T. Haeiwa, K. Naruse, T. Karasawa, Ba-Ferrite Films Prepared by Sol-Gel Pyrolysis Method IEEE Translation Journal on Magnetics in Japan. ,vol. 6, pp. 648- 653 ,(1991) , 10.1109/TJMJ.1991.4565229
O. Ishii, F. Yoshimura, S. Hirono, Magnetization reversal mechanism in .GAMMA.-Fe2O3 thin films. Journal of The Magnetics Society of Japan. ,vol. 15, pp. 93- 96 ,(1991) , 10.3379/JMSJMAG.15.93
H. J. Williams, R. D. Heidenreich, E. A. Nesbitt, Mechanism by Which Cobalt Ferrite Heat Treats in a Magnetic Field Journal of Applied Physics. ,vol. 27, pp. 85- 89 ,(1956) , 10.1063/1.1722202
A López, FJ Lázaro, T González-Carreño, MP Morales, CJ Serna, None, Magnetic properties of γ-Fe2O3 small particles prepared by spray pyrolysis Journal of Magnetism and Magnetic Materials. pp. 383- 384 ,(1995) , 10.1016/0304-8853(94)00793-4
Y. Morikawa, T. Namikawa, Y. Yamazaki, Fe3O4-γFe2O3 中間酸化膜の保磁力に及ぼす内部応力の影響 Journal of The Magnetics Society of Japan. ,vol. 9, pp. 219- 222 ,(1985) , 10.3379/JMSJMAG.9.219
M.V. Cabañas, M. Vallet-Regí, M. Labeau, J.M. González-Calbet, Spherical iron oxide particles synthesized by an aerosol technique Journal of Materials Research. ,vol. 8, pp. 2694- 2701 ,(1993) , 10.1557/JMR.1993.2694